A cost-effective biochar derived from rubber tree sawdust was prepared by low-temperature pyrolysis at 500ºC for 2 h. The biochar was placed as an anode electrode in the anode chamber of the novel model ceramic-separator microbial fuel cell (CMFC) with a laccase-based air cathode. The rubber wastewater (with 500 mg/L sulfate and 1000 mg/L COD) was used as an anolyte. Maximal volumetric power density (PD) of 3.26±0.08 µW/m 3 , maximal volumetric current density of 3.20±0.07 mA/m 3 , and system internal resistance of 1002 Ω were obtained. The post-treatment results showed sulfate removal and COD removal efficiencies of 88.26±1.29% and 89.77±0.45%, respectively. Our work provided a novel model of a low-cost and economically friendly MFC system. Moreover, this work demonstrated a potential route based on sustainable and economical biochar as a bio-anode for wastewater treatment in an MFC.
In this study, three single-chamber microbial fuel cells (MFCs), each having Pt-coated carbon cloth as a cathode and four bamboo charcoal (BC) plates as an anode, were run in a fed-batch mode, individually and in series. Simulated potato-processing wastewater was used as a substrate for supporting the growth of a mixed bacterial culture. The maximum power output increased from 0.386 mW with one MFC to 1.047 mW with three MFCs connected in series. The maximum power density, however, decreased from 576 mW/m2 (normalized to the cathode area) with one MFC to 520 mW/m2 with three MFCs in series. The experimental results showed that power can be increased by connecting the MFCs in series; however, choosing low resistance BC is crucial for increasing power density.
Worldwide applications of ochre analysis continue to develop at a rapid pace, highlighting a number of analytical and interpretative issues. As regional source databases continue to grow, researchers have turned to the thornier issues of source allocation. In this study, we utilize LA-ICP-MS and NAA to examine archaeological pigments, ceramic paints and experimental tiles from geological sources and Hohokam ceramics in central Arizona. Archaeological pigments and paint on sherds are successfully source matched based on trace element content, with implications for understanding paint production, sociocultural relations governing trade in pigment and the use of different resource landscapes over time.
A municipal wastewater treatment plant (WWTP) is a melting pot of numerous pharmaceuticals and personal care products (PPCPs) together with many other substances. The removal of PPCPs using advanced oxidation processes within a WWTP is one way to reduce the amount of PPCPs that potentially enter an aquatic environment. The aim of this study was to examine the effectiveness of the ozone (O3)/UV treatment process, especially, the effects of O3 dose and reaction time, on the removal of PPCPs in the secondary effluent of a WWTP. Experiments were conducted using a pilot-scale treatment process that consisted of two flow-through reactors connected in series. Each reactor was equipped with three 65 W lamps (UV65W). The experimental variables were ozone dosage (1, 2, 3, 4, and 6 mg L−1) and hydraulic retention time (HRT; 5 and 10 min). On the basis of the PPCP concentrations after O3/UV65W treatment and their limit of detection (LOD), 38 PPCPs detected in the secondary effluent were classified into 5 groups ranging from the category of “sensitive” to O3/UV65W or “unstable” in the O3/UV65W process to the category of “insensitive” to O3/UV65W or “very stable” in the O3/UV65W process.
Water, energy, and food are indispensable for sustainable economic development. Despite nutrients, especially phosphorus and nitrogen, being essential for plant growth and thus food supplies, those present in wastewater are considered an environmental burden. While microbial fuel cells (MFCs) are receiving much interest, combining wastewater treatment with an MFC has emerged as an option for low-cost wastewater treatment. Among others, a constructed wetland (CW) coupled with an MFC (CW-MFC) has the potential to provide a low carbon footprint and low-energy wastewater treatment, as well as nutrient and energy recovery from wastewater. Findings from this review show that the organic and nutrient removal and power generation by the integrated CW-MFC systems are affected by a number of factors including the organic loading rate, hydraulic retention time, system design, plant species, dissolved oxygen, substrate/media type, influent feeding mode, electrode materials and spacing, and external resistance. This review aims to summarize the current state of the CW-MFC and related technologies with particular emphasis on organic and nutrient removal, as well as on the bioenergy recovery from different wastewaters. Despite the benefits that these technologies can offer, the interactive mechanisms between the CW and MFC in the integrated system are still unclear. Further research is needed to fully understand the CW-MFC and related systems. The results of this work provide not only an overview and insight into existing knowledge but also the future direction of the CW-MFC technologies.
The world is facing serious threats from the depletion of non-renewable energy resources, freshwater shortages and food scarcity. As the world population grows, the demand for fresh water, energy, and food will increase, and the need for treating and recycling wastewater will rise. In the past decade, wastewater has been recognized as a resource as it primarily consists of water, energy-latent organics and nutrients. Microbial fuel cells (MFC) have attracted considerable attention due to their versatility in their applications in wastewater treatment, power generation, toxic pollutant removal, environmental monitoring sensors, and more. This article provides a review of MFC technologies applied to the removal and/or recovery of nutrients (such as P and N), organics (COD), and bioenergy (as electricity) from various wastewaters. This review aims to provide the current perspective on MFCs, focusing on the recent advancements in the areas of nutrient removal and/or recovery with simultaneous power generation.
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