We have delineated certain important aspects of the use of theoretical Compton profiles for estimating cohesive energy, energy of mixing etc. Inclusion of electron-electron correlation in the calculation of Compton profiles seems to be essential in order to get the correct values of ground state energy differences. We have also done some model calculation for the energy change as a result of 'switching on' correlation in a homogeneous electron gas at zero temperature. Numerical estimates of this 'correlation energy' have been obtained for free-electron-like metals, viz Na and Li.
Intumescent fire-retardant systems have been studied in detail from all points of view. However, all works passed around questions of mechanical stability of foamed chars produced during burning. In the present work, mechanical properties of intumescent chars has been discussed. Technique and method of such investigations have been supposed. It was supposed that mechanical stability of foamed chars correlates with high molecular fraction in char residue.
By means of IR and Raman spectroscopy chemical and physical properties of foamed cokes, formed during combustion and pyrolysis of PP based compositions, containing intumescent fire retardants (IFR) were investigated. It was established that thermal conductivity coefficients of coke material lie in the range of 0.12–0.32 W/m/K and are weakly dependent on the initial composition of IFR. It was shown that the effectiveness of IFR is mainly determined by the internal microstructure of the foamed cokes and the kinetic parameters of their formation.
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