This article presents a method for the electrochemical preparation of a coating of nickel-silica nanocomposites on a carbon steel substrate. The incorporation of hydrophilic silica particles into the Ni composite coating during co-electrodeposition is so difficult due to the small size and the hydrophilicity of SiO 2 particle, generally less than 2 v% of silica is incorporated into the composite at different current densities, agitation speeds and silica concentrations. The effect of the presence of four surfactants, namely cocamidopropyl betaine (CAPB), decylglycoside (DG), cetyltrimethyl ammonium chloride (CTAC) and ammonium lauryl ether sulfate (ALES), on overcoming this problem was investigated in this research, and the surfactants were found to greatly influence the surface charge of silica, silica incorporation percentage and the microstructure of the composite. In fact, upon increasing the internal stresses, the products prepared in the presence of CAPB and DG were found to crack to some degree. CTAC was found to lead to entrapment mode silica co-deposition in the Ni coating. Furthermore, the addition of ALES into an electrolyte bath negatively supercharged silica surfaces and increased silica dispersion, which led to a dramatic increase in the silica incorporation percentages to around 14 v%. The results showed that Ni-SiO 2 composites prepared in the presence of ALES had better corrosion resistance, hardness and wear properties.
ZnO, comprising nanosize particles (approximately 40 nm) has been prepared by heating (300°C) ZnCO3, which was obtained as precipitate by mixing ZnSO4 and (NH4)2CO3 solutions. The prepared ZnO was characterized by X-ray diffraction, scanning electron microscopy (SEM), laser-induced breakdown spectroscopy, and adsorption studies. It has been used to catalyze the decolorization of Ponceau S (PS), a model diazo dye, in an aqueous suspension under visible light (I ≈ 1.8 × 10−4 W cm−2). This ZnO was found to be more efficient as a photocatalyst compared to pristine ZnO. ZnO samples with higher temperatures (500°C and 700°C) show less catalytic activity. SEM images show that the particle size of ZnO increases with the increase in calcined temperature of ZnO through agglomeration, resulting in a decrease in surface area. Photodecolorization of PS is affected by its and ZnO concentrations, but unaffected by the initial pH of the solutions in the range of 4 to 7. Illumination for a sufficiently long time completely mineralizes the dye, but no Zn2+ can be detected in the clear solution.
Photodegradation kinetics in the ZnO suspension obeys the Langmuir-Hinshelwood equation, and some activation of the ZnO surface by light is indicated.
An implementation of inverse kinematic model is applied for the mobile robot using four-wheels mecanum drive. The implementation is designed for omni-directional movement without changes the robot position on a facing direction. Four stepper motors are used to drive the mecanum wheels due to these types have a good precision. This speed control feedback is not necessary. The radius of the mobile robot dimension is defined by the same distance of a and b length between wheel axis and body center of 170 mm. The inverse kinematic is conducted to control the mobile robot movement and to convert the robot velocity component of Vx, Vy, and (J) toward angular velocity each wheels of {J)I, {J)2, {J)3, {J)4 and wheel turn direction. Kinematic calculation and control mechanism are proceed by a master microcontroller and multi-slave microcontrollers which connected using SPI communication protocol. The theta angle (J is described by Vx and Vy vector velocity direction toward center point of the mobile robot. The movement capabilities are performed by linear direction according to the certain angle of the robot movement (J of 00 to each multiples of 450 thus obtained wheel velocity and angle movement average errors.
<span>In this paper, the efficiency of photovoltaic panels is improved by adding a sun tracking system. The solar tracking system is used for tracking the sun so that photovoltaic always faces the sun. This system uses a dual axis consisting of horizontal rotation axis and a vertical rotation axis. The horizontal rotational axis motion is to follow the azimuth angle of the sun from north to south. Then, to follow the sun's azimuth angle from east to west is the vertical axis motion. Both types of movements are controlled using a PID controller that is optimized with an artificial intelligence approach, namely particle swarm optimization (PID-PSO), firefly algorithm (PID-FA), imperialist competitive algorithm (PID-ICA), bat algorithm (PID-BA), and ant colony optimization (PID-ACO). Experiments of various approaches were carried out and the corresponding performance compared. The experimental results show that PID-BA performs best in terms of settling time and overshoot. The results also allow the comparison of different PID controller and the calculation of the fastest completion time.</span>
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