We report a study of crack patterns formed in laponite gel drying in an electric field. The sample dries in a circular petri dish and the field is radial, acting inward or outward. A system of radial cracks forms in the setup with the center terminal positive, while predominantly cross-radial cracks form when the center is at a negative potential. The laponite accumulates near the negative terminal making the layer thicker at this end. A spring model on a square lattice is used to simulate the desiccation crack formation, with an additional radial force acting due to the electric field. With the radial force acting outward, radial cracks form and for the reversed field cross-radial cracks form. This conforms to the observation that laponite platelets become effectively positive due to overcharging and are attracted towards the negative terminal.
We report a study on the kinetics of drying of a droplet of aqueous gelatin containing sodium chloride. The process of drying recorded as a video clearly shows different regimes of growth leading to a variety of crystalline patterns. Large faceted crystals of ∼mm size form in the early stages of evaporation, followed by highly branched multi-fractal patterns with micron sized features. We simulate the growth using a simple algorithm incorporating aggregation and evaporation, which reproduces the cross-over between the two growth regimes. As evaporation proceeds, voids form in the gel film. The time development of the fluid-void system can be characterized by the Euler number. A minimum in the Euler number marks the transition between the two regimes of growth.
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