We report a study of crack patterns formed in laponite gel drying in an electric field. The sample dries in a circular petri dish and the field is radial, acting inward or outward. A system of radial cracks forms in the setup with the center terminal positive, while predominantly cross-radial cracks form when the center is at a negative potential. The laponite accumulates near the negative terminal making the layer thicker at this end. A spring model on a square lattice is used to simulate the desiccation crack formation, with an additional radial force acting due to the electric field. With the radial force acting outward, radial cracks form and for the reversed field cross-radial cracks form. This conforms to the observation that laponite platelets become effectively positive due to overcharging and are attracted towards the negative terminal.

When a colloidal gel dries through evaporation, cracks are usually formed, which often reveal underlying processes at work during desiccation. Desiccating colloid droplets of a few hundred microliters size show interesting effects of pattern formation and cracking which makes this an active subject of current research. Because aqueous gels of clay are known to be strongly affected by an electric field, one may expect crack patterns to exhibit a field effect. In the present study we allow droplets of laponite gel to dry under a radial electric field. This gives rise to highly reproducible patterns of cracks, which depend on the strength, direction, and time of exposure to the electric field. For a continuously applied DC voltage, cracks always appear on dissipation of a certain constant amount of energy. If the field is switched off before cracks appear, the observed results are shown to obey a number of empirical scaling relations, which enable us to predict the time of appearance and the number of cracks under specified conditions. Scanning electron microscopy (SEM) images of the surface between the macroscopic cracks show the presence of microcracks, which are wider and more numerous when no electric field is applied. The microcracks are reduced in the presence of stronger fields.

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We study the crack patterns developed on desiccating films of an aqueous colloidal suspension of bentonite on a glass substrate. Varying the thickness of the layer h gives the following new and interesting results: (i)We identify a critical thickness h c , above which isolated cracks join each other to form a fully connected network.A topological analysis of the crack network shows that the Euler number falls to a minimum at h c . (ii) We find further, that the total vertical surface area of the clay A v , which has opened up due to cracking, is a constant independent of the layer thickness for h ≥ h c . (iii) The total area of the glass substrate A s , exposed by the hierarchical sequence of cracks is also a constant for h ≥ h c . These results are shown to be consistent with a simple energy conservation argument, neglecting dissipative losses. (iv) Finally we show that if the crack pattern is viewed at successively finer resolution, the total cumulative area of cracks visible at a certain resolution, scales with the layer thickness. A suspension of Laponite in methanol is found to exhibit similar salient features (i)-(iv), though in this case the crack initiation process for very thin layers is quite different.

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