The thermal properties of nano-scale materials are largely influenced by their geometry. The zero, one and quasi one dimensional forms of the same material could exhibit unique thermal transport properties depending upon the shape and nano-scale feature size. In order to gain a clear understanding of the contributions from geometrical scattering effects on thermal transport, it is required to study these nano-materials in a single isolated form rather than in clusters or films. In the past decade, titanium dioxide nanotube arrays fabricated by anodic oxidation of titanium emerged as a useful semiconductor architecture for a variety of applications, particularly for solar energy conversion. Nonetheless, the thermal properties of individual nanotubes that are important for their use in high temperature applications have not been clearly understood. Here we report the thermal transport properties of individual titania nanotubes as revealed by our preliminary study using a suspended microdevice that facilitates the thermal conductivity measurements and crystal structure investigation on the same nanotube. The nanotubes were prepared by anodic oxidation of a titanium foil in HF-DMSO electrolyte at 60 V, having outer diameters in the range of 200 to 300 nm and wall thicknesses of ∼30 to 70 nm in either amorphous or polycrystalline anatase phase. The thermal conductivity of single nanotubes was found to be very close to that of the amorphous phase (1.5 W mK(-1) and 0.85 W mK(-1) respectively) and it was only half of the thermal conductivity of the nanotube arrays in the film form. The thermal conductivity of bulk TiO2 is known to be almost six times higher. The observed thermal conductivity suppression in single nanotubes was explained using a transport model developed by considering diffuse phonon-surface scattering and scattering of phonons by ionized impurities of concentrations in the order of 10(18)-10(19) cm(-3).
The effect of physisorbedvs.chemisorbed oxygen on highly organized single walled carbon nanotube (SWCNT) ultrathin films is investigated by correlating the thermoelectric properties measured by a suspended micro-device to the SWCNT structure.
Cobalt ferrite (CoFe2O4)/barium titanate (BaTiO3) particulate composites exhibiting high magnetoelectric coefficients were synthesized from low-cost commercial precursors using mechanical ball milling followed by high-temperature annealing. CoFe2O4 (20 nm–50 nm) and either cubic or tetragonal BaTiO3 nanoparticle powders were used for the synthesis. It was found that utilizing a 50 nm cubic BaTiO3 powder as a precursor results in a composite with a magnetoelectric coupling coefficient value as high as 4.3 mV/Oe cm, which is comparable to those of chemically synthesized core–shell CoFe2O4–BaTiO3 nanoparticles. The microstructure of these composites is dramatically different from the composite synthesized using 200 nm tetragonal BaTiO3 powder. CoFe2O4 grains in the composite prepared using cubic BaTiO3 powder are larger (by at least an order of magnitude) and significantly better electrically insulated from each other by the surrounding BaTiO3 matrix, which results in a high electrical resistivity material. It is hypothesized that mechanical coupling between larger CoFe2O4 grains well embedded in a BaTiO3 matrix in combination with high electrical resistivity of the material enhances the observed magnetoelectric effect.
Functionalized magnetic nanoparticles are increasingly attracting interest as a new and efficient sorbent for metallic contaminant elimination in environmental samples.
This work presents a proof-of-concept demonstration of a novel inductive transducer, the femtoMag, that can be integrated with a lateral-flow assay (LFA) to provide detection and quantification of molecular biomarkers. The femtoMag transducer is manufactured using a low-cost printed circuit board (PCB) technology and can be controlled by relatively inexpensive electronics. It allows rapid high-precision quantification of the number (or amount) of superparamagnetic nanoparticle reporters along the length of an LFA test strip. It has a detection limit of 10−10 emu, which is equivalent to detecting 4 ng of superparamagnetic iron oxide (Fe3O4) nanoparticles. The femtoMag was used to quantify the hCG pregnancy hormone by quantifying the number of 200 nm magnetic reporters (superparamagnetic Fe3O4 nanoparticles embedded into a polymer matrix) immuno-captured within the test line of the LFA strip. A sensitivity of 100 pg/mL has been demonstrated. Upon further design and control electronics improvements, the sensitivity is projected to be better than 10 pg/mL. Analysis suggests that an average of 109 hCG molecules are needed to specifically bind 107 nanoparticles in the test line. The ratio of the number of hCG molecules in the sample to the number of reporters in the test line increases monotonically from 20 to 500 as the hCG concentration increases from 0.1 ng/mL to 10 ng/mL. The low-cost easy-to-use femtoMag platform offers high-sensitivity/high-precision target analyte quantification and promises to bring state-of-the-art medical diagnostic tests to the point of care.
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