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Natural fibers are getting attention from researchers and academician to utilize in polymer composites due to their ecofriendly nature and sustainability. The aim of this review article is to provide a comprehensive review of the foremost appropriate as well as widely used natural fiber reinforced polymer composites (NFPCs) and their applications. In addition, it presents summary of various surface treatments applied to natural fibers and their effect on NFPCs properties. The properties of NFPCs vary with fiber type and fiber source as well as fiber structure. The effects of various chemical treatments on the mechanical and thermal properties of natural fibers reinforcements thermosetting and thermoplastics composites were studied. A number of drawbacks of NFPCs like higher water absorption, inferior fire resistance, and lower mechanical properties limited its applications. Impacts of chemical treatment on the water absorption, tribology, viscoelastic behavior, relaxation behavior, energy absorption flames retardancy, and biodegradability properties of NFPCs were also highlighted. The applications of NFPCs in automobile and construction industry and other applications are demonstrated. It concluded that chemical treatment of the natural fiber improved adhesion between the fiber surface and the polymer matrix which ultimately enhanced physicomechanical and thermochemical properties of the NFPCs.

The world is in need of more eco-friendly material, therefore researchers around the globe focus on developing new materials that would improve the environmental quality of products. This need for new green materials has led to the utilization of composites made from raw natural fibers and polymer matrices, and this has become one of the most widely investigated research topics in recent times. Natural fiber composites are an alternative for replacing environmentally harmful synthetic materials and help control pollution problems. In addition, they are low cost, have better mechanical properties and require low production energy consumption. Also, using such materials in construction works, it is possible to improve the sustainability by eliminating construction wastes. Keeping in view all the benefits of natural fiber reinforced polymer composites, this paper first discusses various fabrication techniques employed for the production of these composites and then presents a detailed review of the research devoted to the analysis of their structure and properties by a variety of characterization techniques.

Dynamic mechanical analysis (DMA) is a versatile technique that complements the information provided by the more traditional thermal analysis techniques such as differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and thermal mechanical analysis (TMA). The dynamic parameters such as storage modulus (E′), loss modulus (E″), and damping factor (Tan δ) are temperature dependent and provide information about interfacial bonding between the reinforced fibre and polymer matrix of composite material. The dynamic parameters were ominously influenced by the increase in fibre length and loading but not in a geometric progression. Dynamic loading conditions are frequently stumble in civil infrastructure systems due to sound, winds, earthquakes, ocean waves and live loads. Vibration damping parameters shows prime importance for structural applications in order to enhance the reliability, performance, buildings comfort and in the alleviation of bridges hazards. DMA also predicts the effects of time and temperature on polymer sealants viscoelastic performance under different environments. Present review article designed to be a comprehensive source of reported literature involving dynamic mechanical properties of natural fibre reinforced polymer composites, hybrid and nano composites and its applications. This review article will provides a perfect data to explore its industrial application primarily as cheaper construction and building materials for doing further research in this topic.

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Abstract:The increasing demand for greener and biodegradable materials leading to the satisfaction of society requires a compelling towards the advancement of nano-materials science. The polymeric matrix materials with suitable and proper filler, better filler/matrix interaction together with advanced and new methods or approaches are able to develop polymeric composites which shows great prospective applications in constructions and buildings, automotive, aerospace and packaging industries. The biodegradability of the natural fibers is considered as the most important and interesting aspects of their utilization in polymeric materials. Nanocomposite shows considerable applications in different fields because of larger surface area, and greater aspect ratio, with fascinating properties. Being environmentally friendly, applications of nanocomposites offer new technology and business opportunities for several sectors, such as aerospace, automotive, electronics, and biotechnology industries. Hybrid bio-based composites that exploit the synergy between natural fibers in a nano-reinforced bio-based polymer can lead to improved properties along with maintaining environmental appeal. This review article intended to present information about diverse classes of natural fibers, nanofiller, cellulosic fiber based composite, nanocomposite, and natural fiber/nanofiller-based hybrid composite with specific concern to their applications. It will also provide summary of the emerging new OPEN ACCESSPolymers 2014, 6 2248 aspects of nanotechnology for development of hybrid composites for the sustainable and greener environment.

The use of starch based films as a potential alternative choice to petroleum derived plastics is imperative for environmental waste management. This study presents a new biopolymer (sugar palm starch) for the preparation of biodegradable packaging films using a solution casting technique. The effect of different plasticizer types (glycerol (G), sorbitol (S) and glycerol-sorbitol (GS) combination) with varying concentrations (0, 15, 30 and 45, w/w%) on the tensile, thermal and barrier properties of sugar palm starch (SPS) films was evaluated. Regardless of plasticizer types, the tensile strength of plasticized SPS films decreased, whereas their elongation at break (E%) increased as the plasticizer concentrations were raised. However, the E% for G and GS-plasticized films significantly decreased at a higher plasticizer concentration (45% w/w) due to the anti-plasticization effect , irrespective of plasticizer types. Overall, the current study manifested that plasticized sugar palm starch can be regarded as a promising biopolymer for biodegradable films.

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