Photoinduced enhanced Raman spectroscopy from a lithium niobate on insulator (LNOI)-silver nanoparticle template is demonstrated both by irradiating the template with 254 nm ultraviolet (UV) light before adding an analyte and before placing the substrate in the Raman system (substrate irradiation) and by irradiating the sample in the Raman system after adding the molecule (sample irradiation). The photoinduced enhancement enables up to an ∼sevenfold increase of the surface-enhanced Raman scattering signal strength of an analyte following substrate irradiation, whereas an ∼threefold enhancement above the surface-enhanced signal is obtained for sample irradiation. The photoinduced enhancement relaxes over the course of ∼10 h for a substrate irradiation duration of 150 min before returning to initial signal levels. The increase in Raman scattering intensity following UV irradiation is attributed to photoinduced charge transfer from the LNOI template to the analyte. New Raman bands are observed following UV irradiation, the appearance of which is suggestive of a photocatalytic reaction and highlight the potential of LNOI as a photoactive surface-enhanced Raman spectroscopy substrate.

Polarization switching in ferroelectric materials underpins a multitude of applications ranging from nonvolatile memories to data storage to ferroelectric lithography. While traditionally considered to be a functionality of the material only, basic theoretical considerations suggest that switching is expected to be intrinsically linked to changes in the electrochemical state of the surface. Hence, the properties and dynamics of the screening charges can affect or control the switching dynamics. Despite being recognized for over 50 years, analysis of these phenomena remained largely speculative. Here, we explore polarization switching on the prototypical LiNbO surface using the combination of contact mode Kelvin probe force microscopy and chemical imaging by time-of-flight mass-spectrometry and demonstrate pronounced chemical differences between the domains. These studies provide a consistent explanation to the anomalous polarization and surface charge behavior observed in LiNbO and point to new opportunities in chemical control of polarization dynamics in thin films and crystals via control of surface chemistry, complementing traditional routes via bulk doping, and substrate-induced strain and tilt systems.

Electronically tunable optical true-time delay lines are proposed. The devices utilize the combination of apodised gratings and the free-carrier plasma effect to tune the enhanced delay of silicon waveguides at a fixed wavelength. Three variations of the proposed scheme are studied and compared. The compact and integrable devices can achieve tuning ranges as high as ~660 ps with a loss of < 2.2 dB when operated in the reflection mode of the gratings. A delay of ~40 ps with a loss of < 10 dB and an estimated operation bit rate of ~20 Gb/s can be achieved.

Several applications in modern photonics require compact on-chip optical filters with a tailored spectral response. However, achieving sub-nanometric bandwidths and high extinction ratios is particularly challenging, especially in low-footprint device formats. Phase shifted Bragg gratings implemented by sidewall modulation of photonic nanowire waveguides are a good solution for on-chip narrowband operation with reasonable requirements in fabrication and scalability. In this work we report on their implementation and optimization in thin film lithium niobate, a photonic platform that affords reconfigurability by exploiting electrooptic effects. The phase-shifted Bragg grating filters have a footprint smaller than 1 μm× 1mm and operate at telecom wavelengths, featuring extinction ratios up to 25 dB. We demonstrate transmission bandwidths as narrow as 14.4 pm (Q = 1.1 x 10 5 ) and 8.8 pm (Q = 1.76 x 10 5 ) in critically coupled structures and multi-wavelength Fabry-Perot configurations, respectively, in full agreement with theoretical predictions. Moreover, by taking advantage of the strong electrooptic effect in lithium niobate, in combination with the tight light confinement of nanophotonic wires and the ultranarrow spectral resonances of optimized grating structures, we demonstrate a tunability of 25.1pm/V and a record modulation of the filter transmission amounting to 1.72 dB/V at CMOS voltages. The results pave the way for reconfigurable narrowband photonic filters in lithium niobate with small footprint and low consumption, to be exploited towards on-chip quantum and nonlinear optics, as well as optical sensing and microwave photonics.

Integration of superconducting devices on photonic platforms opens up a wide range of functionalities and applications. We report on NbTiN thin films deposited on SiO2, Si3N4, GaAs, LiNbO3, and AlN as well as on a monolayer of hexagonal boron nitride, using a universal reactive co-sputtering recipe. The morphology and the superconducting properties of the NbTiN thin films with a thickness of 10 nm were characterized by atomic force microscopy and electrical transport measurements. Superconducting strip photon detectors were fabricated using a design suitable for waveguide integration and compared in terms of their internal quantum efficiency and detection pulse kinetics. Our results show well-comparable performances for detectors integrated on different platforms, while also demonstrating that reactive co-sputter deposition of NbTiN at room temperature provides a robust method for realizing superconducting devices on various materials.

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The preferential deposition of metal nanoparticles onto periodically poled lithium niobate surfaces, whereby photogenerated electrons accumulate in accordance with local electric fields and reduce metal ions from solution, is known to depend on the intensity and wavelength of the illumination and the concentration of the solution used. Here, it is shown that for identical deposition conditions (wavelength, intensity, concentration), post-poling annealing for 10 h at 200 C modifies the surface reactivity through the reorientation of internal defect fields. Whereas silver nanoparticles deposit preferentially on the þz domains on unannealed crystals, the deposition occurs preferentially along 180 domain walls for annealed crystals. In neither case is the deposition selective; limited deposition occurs also on the unannealed -z domain surface and on both annealed domain surfaces. The observed behavior is attributed to a relaxation of the poling-induced defect frustration mediated by Li þ ion mobility during annealing, which affects the accumulation of electrons, thereby changing the surface reactivity. The evolution of the defect field with temperature is corroborated using Raman spectroscopy. V C 2016 AIP Publishing LLC. [http://dx

In vitro devices that combine chemotactic and physical cues are needed for understanding how cells integrate different stimuli. We explored the suitability of lithium niobate (LiNbO3), a transparent ferroelectric material that can be patterned with electrical charge domains and micro/nanotopography, as a neural substrate. On flat LiNbO3 z-surfaces with periodically alternating charge domains, cortical axons are partially aligned with domain boundaries. On submicron-deep etched trenches, neurites are aligned with the edges of the topographical features. Finally, we bonded a bicompartmental microfluidic chip to LiNbO3 surfaces patterned by etching, to create isolated axon microenvironments with predefined topographical cues. LiNbO3 is shown to be an emerging neuron culture substrate with tunable electrical and topographical properties that can be integrated with microfluidic devices, suitable for studying axon growth and guidance mechanisms under combined topographical/chemical stimuli.