Nowadays, studies of alternative liquid insulation in high voltage apparatus have become increasingly important due to higher concerns regarding safety, sustainable resources and environmentally friendly issues. To fulfil this demand, natural ester has been extensively studied and it can become a potential product to replace mineral oil in power transformers. In addition, the incorporation of nanoparticles has been remarkable in producing improved characteristics of insulating oil. Although much extensive research has been carried out, there is no general agreement on the influence on the dielectric response of base oil due to the addition of different amounts and conductivity types of nanoparticle concentrations. Therefore, in this work, a natural ester-based nanofluid was prepared by a two-step method using iron oxide (Fe 2 O 3 ) and titanium dioxide (TiO 2 ) as the conductive and semi-conductive nanoparticles, respectively. The concentration amount of each nanoparticle types was varied at 0.01, 0.1 and 1.0 g/L. The nanofluid samples were characterised by visual inspection, morphology and the dynamic light scattering (DLS) method before the dielectric response measurement was carried out for frequency-dependent spectroscopy (FDS), current-voltage (I-V), and dielectric breakdown (BD) strength. The results show that the dielectric spectra and I-V curves of nanofluid-based iron oxide increases with the increase of iron oxide nanoparticle loading, while for titanium dioxide, it exhibits a decreasing response. The dielectric BD strength is enhanced for both types of nanoparticles at 0.01 g/L concentration. However, the increasing amount of nanoparticles at 0.1 and 1.0 g/L led to a contrary dielectric BD response. Thus, the results indicate that the augmentation of conductive nanoparticles in the suspension can lead to overlapping mechanisms. Consequently, this reduces the BD strength compared to pristine materials during electron injection in high electric fields.

Abstract:In high-voltage insulation systems, the most commonly used material is polymeric material because of its high dielectric strength, high resistivity, and low dielectric loss in addition to good chemical and mechanical properties. In this work, various polymer compounds were prepared, consisting of low-density polyethylene (LDPE), high-density polyethylene (HDPE), polypropylene (PP), HDPE/PP, and LDPE/PP polymer blends. The relative permittivity and breakdown strength of each sample types were evaluated. In order to determine the physical properties of the prepared samples, the samples were also characterized using differential scanning calorimetry (DSC). The results showed that the dielectric constant of PP increased with the increase of HDPE and LDPE content. The breakdown measurement data for all samples were analyzed using the cumulative probability plot of Weibull distribution. From the acquired results, it was found that the dielectric strengths of LDPE and HDPE were higher than that of PP. Consequently, the addition of LDPE and HDPE to PP increased the breakdown strength of PP, but a variation in the weight ratio (30%, 50% and 70%) did not change significantly the breakdown strength. The DSC measurements showed two exothermic crystallization peaks representing two crystalline phases. In addition, the DSC results showed that the blended samples were physically bonded, and no co-crystallization occurred in the produced blends.

This article describes the design of an Ultra-High Frequency (UHF) miniature folded dipole Radio Frequency Identification (RFID) tag antenna that can be mountable on metallic objects. The compact tag antenna is formed from symmetric C-shaped resonators connected with additional arms embedded into the outer strip lines for miniaturization purposes. It is loaded with outer strip lines, resulting in a flexible tuning method that is capable of matching the integrated circuit (IC) chip’s impedance. The proposed tag is fabricated on a single layer of Polytetrafluoroethylene (PTFE) substrate. It has simple structure and does not require any metallic vias or shorting plate. The miniature tag antenna with a size of 82.75 × 19.5 × 1.5   mm 3 yields a total realized gain of − 0.53   dB at the resonance frequency when attached to a 40 × 40   cm 2 metal plate. The presented design utilizes a European RFID band, and the simulated results of realized gain, read range, and input impedance are verified with measurement results.

Hexachlorocyclotriphosphazene is a ring compound consisting of an alternating phosphorus and nitrogen atom with two chlorine substituents attached to the phosphorus atom. The six chlorine atoms attached to this cyclo compound can be substituted with any different nucleophile that leads to changes in different chemical and physical properties. The major topics that were investigated in this research are the flame retardancy and dielectric properties of cyclotriphosphazene compounds. Cyclotriphosphazene compounds have high potential to act as a flame retardant, and this compound consists of two active elements attributed to its high flame-retardant character. This compound also demonstrated good ability as a flame retardant due to its low toxicity and less smoke produced. In addition, cyclotriphosphazene compounds were also investigated for their dielectric properties. Cyclotriphosphazene has high potential in the electrical field since it has dielectric properties that can be widely studied in the investigation of any potential application. This review presented literature studies focused on recent research development and studies in the field of cyclotriphosphazene that focused on synthesis, structural, flame retardancy, and dielectric properties of hexachlorocyclotriphosphazene compounds.

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This study provides a thorough investigation of partial discharge (PD) activities in nanofluid insulation material consisting of different types of nanoparticles, which are conductive and semiconductive when subjected to high voltage stress is presented. Nanofluids have become a topic of interest because they can be an alternative to liquid insulation in electrical apparatus due to their promising dielectric strength and cooling ability. However, during in-service operation, PDs can occur between conductors in the insulation system. Therefore, this study presents the behavior of PDs within nanofluid dielectric materials consisting of conductive and semiconductive nanoparticles. The results show that there is an improvement in the PD resistance and a reduction in the tan delta of nanofluids at power frequency after the incorporation of conductive or semiconductive nanoparticles in the nanofluid oil. However, the most suitable concentration of conductive and semiconductive nanoparticles in the base fluid was found to be, respectively, 0.01 g/L and 1.0 g/L at PD inception and PD steady-state conditions. The clustering of nanoparticles in a nanofluid suspension due to PD activities is also discussed in this study.

In electrical engineering, electrical discharge can occur in gaseous, liquid or solid insulating medium. Localized dielectric breakdown that occur at a small portion of a solid or fluid electrical insulation under high voltage stress is called partial discharge (PD). This phenomenon can cause the material to breakdown if there is no proper action taken. Usually it begins within voids, cracks, or inclusions within a solid dielectric, at conductor-dielectric interfaces within solid and in bubbles within liquid dielectrics. In order to modify electrical properties of the original structure then nanocomposite need to be introduced. Nanocomposite is the original structure that has been inserted by nano component (nanofiller) such as silicone dioxide and titanium dioxide. Nanocomposites are also found in nature, for example in the structure of the abalone shell and bone. By adding nano component inside the original component, it can change the mechanical and electric properties. In this study, PD characteristics of polymer-natural rubber blends nanocomposite have been investigated. The samples of nanocomposites were developed by using extrusion method. The high voltage is applied at the electrode arrangement of the test sample. The signals of partial discharges are detected by CIGRE Method II and RC detector and the signals are transferred to the personal computer using LabViewTM software. The result from the software is analyzed to find out the PD characteristics. The results revealed that the highest PD numbers are compositions with no filler while the lowest PD numbers come from sample that use 4% SiO2 as its nanofiller. The physical morphology observation is also conducted to investigate the degradation of the samples.

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