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Partial oxidation of methane was studied over new Ni nanocatalysts prepared from Ni-impregnated γ-AlOOH, which were compared with their counterparts derived from impregnated γ-Al 2 O 3 and α-Al 2 O 3. The prepared catalysts were characterized by powder X-ray diffraction (XRD), N 2-sorption, H 2-temperatue programmed reduction, scanning electron microscopy, transmission electron microscopy, thermal gravimetric analysis, CO 2-and NH 3-temperatureprogrammed desorption, Raman spectroscopy, CO chemisorption, and diffuse reflectance infrared Fourier transform spectroscopy of adsorbed CO. Employing γ-AlOOH as the support precursor resulted in significantly improved textural properties and catalytic activity. The structure of the support precursor and its surface properties showed a strong influence on the type of Ni active species and their interactions with the support. γ-AlOOH-derived catalysts showed NiO as the dominant Ni species when calcined at 500 C to 650 C, while NiAl 2 O 4 became the sole phase at higher temperatures. On the other hand, mixtures of NiO and NiAl 2 O 4 formed over γ-Al 2 O 3 , calcined before impregnation, regardless of the precalcination temperature. All γ-AlOOHderived catalysts showed higher specific surface areas compared to their counterparts derived from impregnated γ-Al 2 O 3. Upon calcination at moderate temperatures, γ-AlOOH-derived catalysts also showed modified textural and morphological properties of the Ni active particles, including higher Ni dispersion, larger metal surface area, and smaller Ni crystallites. The support precursor and the pretreatment conditions showed a strong influence on the catalytic performance, which was referred to their significant effect on the type of the Ni species and interactions with the support. All catalysts showed higher catalytic activity than the α-Al 2 O 3-derived catalyst, with CH 4 conversion between 86% and 88.5% at 700 C. While γ-AlOOHand γ-Al 2 O 3-derived catalysts calcined at 650 C showed a stable CH 4 conversion around 88%, and higher syngas