The first evidence for ultrahigh‐pressure (UHP) metamorphism in the Eastern Alps is reported from kyanite eclogites of the Pohorje Mountains in Slovenia. Polycrystalline quartz inclusions surrounded by radial fractures in garnet, omphacite, and kyanite are interpreted to be pseudomorphs after coesite. Abundant quartz rods and needles in omphacite indicate an exsolution from a preexisting supersilicic clinopyroxene that contained a Ca‐Eskola component. Geothermobarometry on the mineral assemblage garnet + omphacite + kyanite + phengite + quartz/or coesite yields peak pressure and temperature conditions of 3.0–3.1 GPa and 760°–825°C, well within the stability field of coesite, thus supporting the microtextural evidence for UHP metamorphism. This records the highest‐pressure conditions of Eo‐Alpine metamorphism during the Cretaceous orogeny in the Alps, implying a very deep subduction of the continental crust to at least 90–100 km depths. The new data are evidence for a regional southeastward increase of peak pressures in the Lower Central Austroalpine, indicating a south‐ to eastward dip of the subduction zone. Subduction was intracontinental; northwestern parts of the Austroalpine (Lower Central Austroalpine) were subducted under southeastern parts (Upper Central Austroalpine). The subduction zone formed in the Early Cretaceous in the northwestern foreland of the Meliata suture after Late Jurassic closure of the Meliata Ocean and the resulting collision, by a forward subduction shift to a Permian rift.
We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp3‐bonded carbon, in most cases centred between 1332 and 1330 cm−1, with a full width at half maximum between 3 and 5 cm−1. Several spectra show Raman bands typical for disordered graphitic (sp2‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO2 and CH4 in polyphase inclusions. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.
A sustainable solution for the global construction industry can be partial substitution of Ordinary Portland Cement (OPC) by use of supplementary cementitious materials (SCMs) sourced from industrial end-of-life (EOL) products that contain calcareous, siliceous and aluminous materials. Candidate EOL materials include fly ash (FA), silica fume (SF), natural pozzolanic materials like sugarcane bagasse ash (SBA), palm oil fuel ash (POFA), rice husk ash (RHA), mine tailings, marble dust, construction and demolition debris (CDD). Studies have revealed these materials to be cementitious and/or pozzolanic in nature. Their use as SCMs would decrease the amount of cement used in the production of concrete, decreasing carbon emissions associated with cement production. In addition to cement substitution, EOL products as SCMs have also served as coarse and also fine aggregates in the production of eco-friendly concretes.
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