The first evidence for ultrahigh‐pressure (UHP) metamorphism in the Eastern Alps is reported from kyanite eclogites of the Pohorje Mountains in Slovenia. Polycrystalline quartz inclusions surrounded by radial fractures in garnet, omphacite, and kyanite are interpreted to be pseudomorphs after coesite. Abundant quartz rods and needles in omphacite indicate an exsolution from a preexisting supersilicic clinopyroxene that contained a Ca‐Eskola component. Geothermobarometry on the mineral assemblage garnet + omphacite + kyanite + phengite + quartz/or coesite yields peak pressure and temperature conditions of 3.0–3.1 GPa and 760°–825°C, well within the stability field of coesite, thus supporting the microtextural evidence for UHP metamorphism. This records the highest‐pressure conditions of Eo‐Alpine metamorphism during the Cretaceous orogeny in the Alps, implying a very deep subduction of the continental crust to at least 90–100 km depths. The new data are evidence for a regional southeastward increase of peak pressures in the Lower Central Austroalpine, indicating a south‐ to eastward dip of the subduction zone. Subduction was intracontinental; northwestern parts of the Austroalpine (Lower Central Austroalpine) were subducted under southeastern parts (Upper Central Austroalpine). The subduction zone formed in the Early Cretaceous in the northwestern foreland of the Meliata suture after Late Jurassic closure of the Meliata Ocean and the resulting collision, by a forward subduction shift to a Permian rift.

New evidence for ultrahigh-pressure metamorphism (UHPM) in the Eastern Alps is reported from garnet-bearing ultramafic rocks from the Pohorje Mountains in Slovenia. The garnet peridotites are closely associated with UHP kyanite eclogites. These rocks belong to the Lower Central Austroalpine basement unit of the Eastern Alps, exposed in the proximity of the Periadriatic fault. Ultramafic rocks have experienced a complex metamorphic history. On the basis of petrochemical data, garnet peridotites could have been derived from depleted mantle rocks that were subsequently metasomatized by melts and/or fluids either in the plagioclase-peridotite or the spinel-peridotite field. At least four stages of recrystallization have been identified in the garnet peridotites based on an analysis of reaction textures and mineral compositions. Stage I was most probably a spinel peridotite stage, as inferred from the presence of chromian spinel and aluminous pyroxenes. Stage II is a UHPM stage defined by the assemblage garnet + olivine + low-Al orthopyroxene + clinopyroxene + Cr-spinel. Garnet formed as exsolutions from clinopyroxene, coronas around Cr-spinel, and porphyroblasts. Stage III is a decompression stage, manifested by the formation of kelyphitic rims of high-Al orthopyroxene, aluminous spinel, diopside and pargasitic hornblende replacing garnet. Stage IV is represented by the formation of tremolitic amphibole, chlorite, serpentine and talc. Geothermobarometric calculations using (i) garnet-olivine and garnet-orthopyroxene Fe-Mg exchange thermometers and (ii) the Al-inorthopyroxene barometer indicate that the peak of metamorphism (stage II) occurred at conditions of around 900°C and 4 GPa. These results suggest that garnet peridotites in the Pohorje Mountains experienced UHPM during the Cretaceous orogeny. We propose that UHPM resulted from deep subduction of continental crust, which incorporated mantle peridotites from the upper plate, in an intracontinental subduction zone. Sinking of the overlying mantle and lower crustal wedge into the asthenosphere (slab extraction) caused the main stage of unroofing of the UHP rocks during the Upper Cretaceous. Final exhumation was achieved by Miocene extensional core complex formation.

The recent discovery of ultrahigh-pressure (UHP) mineral parageneses in the far-transported (greater than 400 km) Seve Nappe Complex of the Swedish Caledonides sheds new light on the subduction system that dominated the contracting Baltoscandian margin of continental Baltica during the Ordovician and culminated in collision with Laurentia in the Silurian to Early Devonian. High-grade metamorphism of this Neoproterozoic to Cambrian rifted, extended, dike-intruded outer-margin assemblage started in the Early Ordovician and may have continued, perhaps episodically, until collision of the continents at the end of this period. The recent discovery of UHP kyanite eclogite in northern Jämtland (west-central Sweden) yields evidence of metamorphism at depths of 100 km. Although UHP rocks are only locally preserved from retrogression during the long-distance transport onto the Baltoscandian platform, these high-pressure parageneses indicate that deep subduction played an important role in the tectonothermal history of the complex. Based on existing isotopic age data, this UHP metamorphism occurred in the Late Ordovician, shortly before, or during, the initial collision between the continents (Scandian orogeny). In some central parts of the complex, migmatization and hot extrusion occurred in the Early Silurian, giving way to thrust emplacement across the Baltoscandian foreland basin and platform that continued into the Early Devonian. Identifi cation of HP/UHP metamorphism at different levels within the Scandian allochthons, defi nition of their pressure-temperature-time paths, and recognition of their vast transport distances are essential for an understanding of the deeper structural levels of the orogen in the hinterland (e.g., the Western Gneiss Region), where the attenuated units were reworked together during the Early Devonian.

[1] The Nestos Shear Zone (NSZ) in the Rhodope Metamorphic Province is a major high-strain zone between two metamorphic terranes. Microdiamond-bearing ultrahigh-pressure (UHP) rocks occur in the NSZ which was therefore interpreted as a suture zone where subduction and exhumation of these rocks and terrain accretion occurred during the Mesozoic. Our petrological study of samples from the lower part of the NSZ, together with monazite dating of a microdiamond-bearing garnet schist, structural observations, already published results from the upper part, and other published timing constraints, results in a fundamentally different picture: the NSZ is the base of an Eocene age southwestward thrust wedge which included not only the structurally higher parts of the Rhodope Metamorphic Province but also the entire Internal Hellenides. The UHP rocks, for the peak pressure of which we derive an age of ∼200 Ma by monazite dating, are unrelated to the tectonic processes in the NSZ and probably represent slivers of a higher tectonic unit captured by thrusting along the NSZ. Pressure decrease in the footwall and regional extension and basin formation in the hanging wall during the activity of the NSZ show that the overlying thrust wedge was collapsing in late Eocene times. We hypothesize that the transition from subduction to continental collision may start with a pronounced accretion event when the first detachment horizon forms in the middle crust of the downgoing plate. Such an event could trigger slab retreat, an extensional collapse of the internal wedge, and subsequent magmatism.

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We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp3‐bonded carbon, in most cases centred between 1332 and 1330 cm−1, with a full width at half maximum between 3 and 5 cm−1. Several spectra show Raman bands typical for disordered graphitic (sp2‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO2 and CH4 in polyphase inclusions. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.

Metamorphic diamond in crustal rocks provides important information on the deep subduction of continental crust. Here, we present a new occurrence of diamond within the Seve Nappe Complex (SNC) of the Scandinavian Caledonides, on Åreskutan in Jämtland County, Sweden. Microdiamond is found in situ as single and composite (diamond+carbonate) inclusions within garnet, in kyanite‐bearing paragneisses. The rocks preserve the primary peak pressure assemblage of Ca,Mg‐rich garnet+phengite+kyanite+rutile, with polycrystalline quartz surrounded by radial cracks indicating breakdown of coesite. Calculated P–T conditions for this stage are 830–840 °C and 4.1–4.2 GPa, in the diamond stability field. The ultrahigh‐pressure (UHP) assemblage has been variably overprinted under granulite facies conditions of 850–860 °C and 1.0–1.1 GPa, leading to formation of Ca,Mg‐poor garnet+biotite+plagioclase+K‐feldspar+sillimanite+ilmenite+quartz. This overprint was the result of nearly isothermal decompression, which is corroborated by Ti‐in‐quartz thermometry. Chemical Th–U–Pb dating of monazite yields ages between 445 and 435 Ma, which are interpreted to record post‐UHP exhumation of the diamond‐bearing rocks. The new discovery of microdiamond on Åreskutan, together with other evidence of ultrahigh‐pressure metamorphism (UHPM) within gneisses, eclogites and peridotites elsewhere in the SNC, provide compelling arguments for regional (at least 200 km along strike of the unit) UHPM of substantial parts of this far‐travelled allochthon. The occurrence of UHPM in both rheologically weak (gneisses) and strong lithologies (eclogites, peridotites) speaks against the presence of large tectonic overpressure during metamorphism.