X-ray phase analysis (XRD), differential thermal analysis (DTA) and X-ray fluorescence spectroscopy (XRF) of pyrite samples in a protective (Ar) and an oxidative atmosphere (air) at different temperatures (200, 300, 500, 700)°C and times (1, 2, 4) h were made. A graphical representation of the unit cell of magnetic pyrrhotite and diffraction patterns of the individual crystal structures of pyrite, which occur in the sample at selected temperatures, atmosphere, and exposure times were analyzed with X-ray diffraction software (CrystalMaker). The results show that FeS2 exhibited temperature-dependent changes in the crystal structure that are not included in current Fe-S phase diagrams. Keywords: Pohorje, Eastern Alps, structural changes, FeS 2 pyrite, XRD, XRF, DTA Vzorci pirita so bili analizirani s pomo~jo rentgenske fazne analize (XRD), diferen~ne termi~ne analize (DTA) in rentgenske fluorescentne spektroskopije (XRF) po`arjenju v za{~itni (Ar) in oksidativni atmosferi (zrak) pri razli~nih temperaturah (200, 300, 500 in 700)°C in~asih (1, 2 in 4) h. S programsko opremo (CrystalMaker) je grafi~no predstavljena osnovna celica magnetnega pirotita. Analizirani so tudi rentgenogrami posameznih kristalnih struktur pirita, ki se pojavijo v vzorcu pri dolo~enih temperaturah, atmosferi in~asih`arjenja. Rezultati ka`ejo, da pirit izkazuje temperaturno odvisne spremembe v kristalni strukturi, ki niso vklju~ene v dosedanje fazne diagrame Fe-S.