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In the general framework of quantitative methods for natural-technological (NaTech) risk analysis, a specific methodology was developed for assessing risks caused by hazardous substances released due to earthquakes. The contribution of accidental scenarios initiated by seismic events to the overall industrial risk was assessed in three case studies derived from the actual plant layout of existing oil refineries. Several specific vulnerability models for different equipment classes were compared and assessed. The effect of differing structural resistances for process equipment on the final risk results was also investigated. The main factors influencing the final risk values resulted from the models for equipment vulnerability and the assumptions for the reference damage states of the process equipment. The analysis of case studies showed that in seismic zones the additional risk deriving from damage caused by earthquakes may be up to more than one order of magnitude higher than that associated to internal failure causes. Critical equipment was determined to be mainly pressurized tanks, even though atmospheric tanks were more vulnerable to containment loss. Failure of minor process equipment having a limited hold-up of hazardous substances (such as pumps) was shown to have limited influence on the final values of the risk increase caused by earthquakes.

Natural hazards and disasters can cause major accidents in chemical and process installations. These so-called Natech accidents can result in hazardous-materials releases due to damage to process and storage units, or pipes. In order to understand the dynamics of Natech events, accidents triggered by earthquakes, floods and lightning recorded in industrial accident databases were analysed. This allowed the identification of the most vulnerable equipment types, their modes of failure due to natural-event impact and the final accident scenarios. Moreover, lessons learned for future accident prevention and mitigation were derived. The analysis showed that pipes and storage tanks are the most vulnerable equipment for earthquakes, floods and lightning, calling for more research of equipment behaviour under natural-event loading. The damage modes and states are strongly dependent on the characteristics of the impacting natural event. Toxic dispersion, fires and explosions were observed as a consequence of all three types of analysed natural events. In the case of floods, two additional scenarios were identified. These are water contamination and the formation of toxic and/or flammable vapours upon reaction of the released chemicals with the floodwaters. The overall number of recorded Natech accidents was found to range from 2 to 5% of all reported accidents in the analysed databases.

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