Non-volatile memories will play a decisive role in the next generation of digital technology. Flash memories are currently the key player in the field, yet they fail to meet the commercial demands of scalability and endurance. Resistive memory devices, and in particular memories based on low-cost, solution-processable and chemically tunable organic materials, are promising alternatives explored by the industry. However, to date, they have been lacking the performance and mechanistic understanding required for commercial translation. Here we report a resistive memory device based on a spin-coated active layer of a transition-metal complex, which shows high reproducibility (∼350 devices), fast switching (≤30 ns), excellent endurance (∼10 cycles), stability (>10 s) and scalability (down to ∼60 nm). In situ Raman and ultraviolet-visible spectroscopy alongside spectroelectrochemistry and quantum chemical calculations demonstrate that the redox state of the ligands determines the switching states of the device whereas the counterions control the hysteresis. This insight may accelerate the technological deployment of organic resistive memories.
The wetting behaviour of surfaces is believed to be affected by van der Waals (vdW) forces; however, there is no clear demonstration of this. With the isolation of two-dimensional vdW layered materials it is possible to test this hypothesis. In this paper, we report the wetting behaviour of vdW heterostructures which include chemical vapor deposition (CVD) grown graphene, molybdenum disulfide (MoS2) and tungsten disulfide (WS2) on few layers of hexagon boron nitride (h-BN) and SiO2/Si. Our study clearly shows that while this class of two-dimensional materials are not completely wetting transparent, there seems to be a significant amount of influence on their wetting properties by the underlying substrate due to dominant vdW forces. Contact angle measurements indicate that graphene and graphene-like layered transitional metal dichalcogenides invariably have intrinsically dispersive surfaces with a dominating London-vdW force-mediated wettability.
Characterization of nanomechanical graphene drum structures is presented in this paper. The structures were fabricated by mechanical exfoliation of graphite onto pre-etched circular trenches in silicon dioxide on a silicon substrate. Drum structures with diameters ranging from 3.8 to 5.7 μm and thicknesses down to 8 nm were achieved. Mechanical characterization of the devices was then carried out by using atomic force microscopy (AFM) to measure their electrostatic deflection. The structures were found to have linear spring constants ranging from 3.24 to 37.4 N m −1 and could be actuated to about 18-34% of their thickness before exhibiting nonlinear deflection. An analytical framework was formulated to model the deflection behaviour which was verified through finite element simulations (FEM). The experimental measurements agree well with analytical and finite element results using Young's modulus of 1 TPa. The resonance characteristics of the structures were derived by both plate theory and FEM simulations. It was found that our drum structures could potentially vibrate at frequencies in excess of 25 MHz. The small size and high operating frequencies of our nanomechanical graphene devices make them very promising for resonant mass sensing applications with 10 −20 g Hz −1 sensitivity, a two order of magnitude improvement over other reported silicon structures.
Multifunctional coatings offer many advantages towards protecting various surfaces. Here we apply aggregation induced segregation of perylene diimide (PDI) to control the surface morphology and properties of silica nanoparticles. Differentially functionalized PDI was incorporated on the surface of silica nanoparticles through Si-O-Si bonds. The absorption and emission spectra of the resultant functionalised nanoparticles showed monomeric or excimeric peaks based on the amounts of perylene molecules present on the surface of silica nanoparticles. Contact angle measurements on thin films prepared from nanoparticles showed that unfunctionalised nanoparticles were superhydrophilic with a contact angle (CA) of 0°, whereas perylene functionalised silica particles were hydrophobic (CA > 130°) and nanoparticles functionalised with PDI and trimethoxy(octadecyl)silane (TMODS) in an equimolar ratio were superhydrophobic with static CA > 150° and sliding angle (SA) < 10°. In addition, the near infrared (NIR) reflectance properties of PDI incorporated silica nanoparticles can be used to protect various heat sensitive substrates. The concept developed in this paper offers a unique combination of super hydrophobicity, interesting optical properties and NIR reflectance in nanosilica, which could be used for interesting applications such as surface coatings with self-cleaning and NIR reflection properties.
In this paper, a simple and effective experimental approach has been used to extract the mechanical properties of suspended nanomechanical graphene devices using atomic force microscopy (AFM). The main objective of this work is to study the deflection behaviour of graphene devices as a function of layer number (1-5 layers) and anchor geometry which has not been widely investigated so far. Elastic and nonlinear responses of the devices were obtained using AFM nanoindentation. The estimated linear (2.5 N m −1 to 7.3 N m −1 ), nonlinear spring constants (1 × 10 14 N m −3 to 15 × 10 14 N m −3 ) and pretension (0.79 N m −1 to 2.3 N m −1 ) for the monolayer (3.35 Å) to five layer (16.75 Å) graphene devices of diameter 3.8 μm show an obvious increasing trend with increase in graphene thickness. The effect of anchor geometry on the force versus deflection behaviour of these devices has also been investigated. The Raman spectroscopy results confirm the absence of defects in the pristine and indented devices. Using the continuum mechanics model, the Young's modulus and 2D elastic modulus of a monolayer graphene device have been found to be 1.12 TPa and 375 N m −1 respectively. The high stiffness and low mass of these devices make them well suited for sensing applications.
Reduced graphene oxide (rGO) has attracted significant interest in an array of applications ranging from flexible optoelectronics, energy storage, sensing, and very recently as membranes for water purification. Many of these applications require a reproducible, scalable process for the growth of large-area films of high optical and electronic quality. In this work, we report a one-step scalable method for the growth of reduced-graphene-oxide-like (rGO-like) thin films via pulsed laser deposition (PLD) of sp2 carbon in an oxidizing environment. By deploying an appropriate laser beam scanning technique, we are able to deposit wafer-scale uniform rGO-like thin films with ultrasmooth surfaces (roughness <1 nm). Further, in situ control of the growth environment during the PLD process allows us to tailor its hybrid sp2–sp3 electronic structure. This enables us to control its intrinsic optoelectronic properties and helps us achieve some of the lowest extinction coefficients and refractive index values (0.358 and 1.715, respectively, at 2.236 eV) as compared to chemically grown rGO films. Additionally, the transparency and conductivity metrics of our PLD grown thin films are superior to other p-type rGO films and conducting oxides. Unlike chemical methods, our growth technique is devoid of catalysts and is carried out at lower process temperatures. This would enable the integration of these thin films with a wide range of material heterostructures via direct growth.
In this manuscript, we demonstrate a method based on atomic force microscopy which enables local probing of surface wettability. The maximum pull-off force, obtained from force spectroscopy shows a remarkable correlation with the macroscopically observed water contact angle, measured over a wide variety of surfaces starting from hydrophilic, all the way through to hydrophobic ones. This relationship, consequently, facilitates the establishment of a universal behaviour. The adhesion forces scale with the polar component of surface energy. However, no such relation could be established with the dispersive component. Hence, we postulate that the force(s) which enable us to correlate the force spectroscopy data measured on the nanoscale to the macroscopic contact angle are primarily arising from electrostatic-dipole-dipole interactions at the solid-liquid interface. London forces play less of a role. This effect in is line with density functional theory (DFT) calculations suggesting a higher degree of hydroxylation of hydrophilic surfaces. This result shows that molecular simulations and measurements on an atomic scale can be extrapolated to macroscopic surface wetting problems.
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