Acting as artificial synapses, two‐terminal memristive devices are considered fundamental building blocks for the realization of artificial neural networks. Current memristive crossbar architectures demonstrate the implementation of neuromorphic computing paradigms, although they are unable to emulate typical features of biological neural networks such as high connectivity, adaptability through reconnection and rewiring, and long‐range spatio‐temporal correlation. Herein, self‐organizing memristive random nanowire (NW) networks with functional connectivity able to display homo‐ and heterosynaptic plasticity is reported thanks to the mutual electrochemical interaction among memristive NWs and NW junctions. In particular, it is shown that rewiring and reweighting effects observed in single NWs and single NW junctions, respectively, are responsible for structural plasticity of the network under electrical stimulation. Such biologically inspired systems allow a low‐cost realization of neural networks that can learn and adapt when subjected to multiple external stimuli, emulating the experience‐dependent synaptic plasticity that shape the connectivity and functionalities of the nervous system that can be exploited for hardware implementation of unconventional computing paradigms.

The measurements of dc Josephson and quasiparticle current-voltage characteristics of four-layered Nb/Al–AlOx–Nb devices with a fixed Nb thickness of 270 nm and Al thicknesses ranging from 40 to 120 nm are reported and analyzed in the framework of a microscopic model developed to determine stationary properties of dirty limit double-barrier junctions. It is shown that the temperature dependence of the supercurrent as well as the values of characteristic voltages are well reproduced by the model calculations with only one fitting parameter. We have revealed a hysteretic-to-nonhysteretic transition in the current-voltage characteristics of our junctions at temperatures near 4.2 K and argue that this effect is caused by two factors: high-transparency insulating barrier with a broad distribution of the transmission coefficient and the temperature as a tuning parameter, which decreases the McCumber–Stewart parameter from values above unity at low temperatures to less than one above 4.2 K. Finally, we show how and why the temperature stability of the proposed Josephson devices can be significantly improved by choosing an appropriate Al thickness.

Superconducting and normal state properties of Niobium nanofilms have been systematically investigated as a function of film thickness, on different substrates. The width of the superconducting-to-normal transition for all films is remarkably narrow, confirming their high quality. The superconducting critical current density exhibits a pronounced maximum for thickness around 25 nm, marking the 3D-to-2D crossover. The magnetic penetration depth shows a sizeable enhancement for the thinnest films. Additional amplification effects of the superconducting properties have been obtained with sapphire substrates or squeezing the lateral size of the nanofilms. For thickness close to 20 nm we measured a doubled perpendicular critical magnetic field compared to its large thickness value, indicating shortening of the correlation length and the formation of small Cooper pairs. Our data analysis indicates an exciting interplay between quantum-size and proximity effects together with strong-coupling effects and the importance of disorder in the thinnest films, placing these nanofilms close to the BCS-BEC crossover regime.

We report low-temperature measurements of current-voltage characteristics for highly conductive Nb/Al-AlO x -Nb junctions with thicknesses of the Al interlayer ranging from 40 to 150 nm and ultrathin barriers formed by diffusive oxidation of the Al surface. In a superconducting state these devices have revealed a strong subgap current leakage. Analyzing Cooper-pair and quasiparticle currents across the devices, we conclude that the strong suppression of the subgap resistance compared with conventional tunnel junctions is not related to technologically derived pinholes in the barrier but rather has more fundamental grounds. We argue that it originates from a universal bimodal distribution of transparencies across the aluminum oxide barrier proposed earlier by Schep and Bauer (1997 Phys. Rev. Lett. 78 3015). We suggest a simple physical explanation of its source in the nanometer-thick oxide films relating it to strong local barrier-height fluctuations in the nearest to conducting electrode layers of the insulator which are generated by oxygen vacancies in thin aluminum oxide tunnel barriers formed by thermal oxidation.

We present an ultra high sensitive three-dimensional nano Superconducting QUantum Interference Device (nanoSQUID) fabricated by using the Focused Ion Beam sculpting technique. Based on a fully niobium technology, the nanodevice consists in a niobium superconducting loop (0.2 μm2) interrupted by two nanometric Nb/Al-AlOx/Nb Josephson junctions. The nanoSQUID exhibited an intrinsic magnetic flux noise as low as 0.65 μΦ0/Hz1/2 corresponding to a spin noise less than 10 Bohr magnetons per unit of bandwidth. It has been successfully employed in nanoparticle magnetic relaxation measurements. Due to its excellent performance, reliability, and robustness, we believe that the proposed nanoSQUID offers a crucial step toward a wide employment of nanoSQUIDs in the nanoscience

Neuromorphic Systems In article number http://doi.wiley.com/10.1002/aisy.202000096, Daniele Ielmini, Ilia Valov, Carlo Ricciardi, and co‐workers report a brain‐inspired complex system based on self‐organizing memristive nanowire networks with functional connectivity that exhibit structural plasticity including rewiring and reweighting effects. These neuromorphic systems allow the realization of neural networks with heterosynaptic plasticity able to learn and adapt when subjected to external stimuli, emulating the experience‐dependent plasticity of the nervous system.

We describe the first use of a novel photoresist-free X-ray nanopatterning technique to fabricate an electronic device. We have produced a proof-of-concept device consisting of a few Josephson junctions by irradiating microcrystals of the Bi2Sr2CaCu2O8+δ (Bi-2212) superconducting oxide with a 17.6 keV synchrotron nanobeam. Fully functional devices have been obtained by locally turning the material into a nonsuperconducting state by means of hard X-ray exposure. Nano-XRD patterns reveal that the crystallinity is substantially preserved in the irradiated areas that there is no evidence of macroscopic crystal disruption. Indications are that O ions have been removed from the crystals, which could make this technique interesting also for other oxide materials. Direct-write X-ray nanopatterning represents a promising fabrication method exploiting material/material rather than vacuum/material interfaces, with the potential for nanometric resolution, improved mechanical stability, enhanced depth of patterning, and absence of chemical contamination with respect to traditional lithographic techniques.

The metal assisted etching mechanism for Si nanowire fabrication, triggered by doping type and level and coupled with choice of metal catalyst, is still very poorly understood. We explain the different etching rates and porosities of wires we observe based on extensive experimental data, using a new empirical model we have developed. We establish as a key parameter, the tunneling through the space charge region (SCR) which is the result of the reduction of the SCR width by level of the Si wafer doping in the presence of the opposite biases of the p- and n-type wafers. This improved understanding should permit the fabrication of high quality wires with predesigned structural characteristics, which hitherto has not been possible.