Ionomeric Polymer-Metal Composites (IPMC) are smart materials whose electromechanical behavior depends on the electrical stimulus intensity, membrane hydration level, and ionic migration. This paper investigates the effects of the voltage, relative humidity, and counterion type (Li + and K + ) on a Nafion-based IPMC performance. Instrumentation capable of applying an electrical stimulus and measuring the electromechanical response was developed. The ionic conductivity was obtained using Electrochemical Impedance Spectroscopy. Complementary SEM analyses were performed before and after actuation cycles. The IPMC performance improved when the electrical stimulus was 5.00 V, RH = 90%, and Li + was used. The IPMC-Li sample is an excellent candidate to be used as an actuator since it exhibited fast actuation movement, considerable displacement, and no evident back-relaxation. However, its mechanical performance decreased over time because of a progressive increase in platinum electrode crack density and dehydration. The video analysis technique is an efficient, effective, and low-cost technique.
Ionomeric Polymer-Metal Composites (IPMCs) are sandwich-like materials based in a polymeric membrane covered on both sides by metallic electrodes. Its operation mechanism consists of hydrated ions migration in response to an external electrical field generated between the electrodes, leading to a spatially nonuniform mass accumulation which causes the device to bend. Its performance as an actuator depends mainly on the environment's relative humidity and electrical stimuli. Consequently, IPMCs present variations in the electromechanical properties exhibiting nonlinearities and time-varying behaviors, limiting the major applications. For this reason, this paper investigated a PI controller performance to overcome these drawbacks and effectively control a Nafion-based IPMC-Li + exposed to different relative humidities and electrical stimulis. The PI control system uses a camera with a machine vision application as a feedback sensor. Support instrumentation was developed to control the relative humidity, apply an electrical stimulus, and measure the electromechanical response. The pattern recognition algorithm implemented in the controller is efficient, with accuracy above 95%, making the feedback sensor reliable. Therefore, the PI controller was effective, stable, and capable of controlling and characterizing IPMC devices when relative humidity was above 60% at a low-frequency displacement and avoided the undesired back-relaxation phenomenon.
Conductive polymeric composites are exciting for future electronic applications given the possibility to ally electrical conductivity and flexibility. However, the high viscosity of plasticized elastomers difficult the dispersion of conductive fillers in an elastomeric matrix is difficult. This research aimed to compare the use of bath or probe sonication to disperse multi-walled carbon nanotubes (MWCNT) in the lower-viscosity natural rubber latex. The MWCNT concentration varied from 0.5 to 2.5 wt%, and the coagulated compounds were vulcanized after compounding in a two-roll mill. Nanocomposite's swelling behavior was determined by Flory-Rehner crosslink density and Kraus theory, indicating better dispersion in probe sonication, which also was conducted in lesser time and applied lower energy than bath sonication. This result is evidenced through tensile strength and hardness tests, as the better MWCNT dispersion improved the reinforcement due to greater filler-matrix interaction. The electrical response was obtained by impedance spectroscopy, with higher conductivities also found in tip-sonicated samples.In addition, cyclic strain fatigue test was realized from 20% to 100% strain during 20,000 cycles with simultaneous impedance measurement, reinforcing the better distribution of MWCNT in the probe-sonicated nanocomposites with higher tensile stress (Payne's effect) and conductivity retention than bath sonicated.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.