This study aims to analyze the efficiency of niobium and vanadium carbides in the high energy mechanical milling of aluminum bronze alloy. Two series of experiments were made following the same steps for both niobium carbide (NbC) and vanadium carbide (VC) additions: 30 g of chips were weighed and placed in a stainless steel jar with 3 % of carbide and 1 % of stearic acid for a mass/sphere relationship of 1:10. The milling was realized using a planetary ball mill for 10, 30 and 50 hours in an inert argon atmosphere at 300 rpm. Results shown in laser diffraction indicate a great reduction in the particle sizes of powders when VC is used. For 30 hours milling, D50 values ranged from 1580 μm with NbC to 182.3 μm with VC addition. The D50 values ranged from 251.5 μm with NbC to 52.26 μm with VC addition, for 50 hours milling. The scanning electron microscopy showed that in 10 hours of milling, the energy was not sufficient to achieve the shear of chips in both cases. For 30 hours, it's possible to observe particles with sizes between 100 μm and 800 μm with NbC addition while for the same milling time, with VC it's possible to see particles with different sizes, but with many shapes of fine particulates. For 50 hours milling, particles achieved the smaller sizes between 50 and 200 μm with NbC and ranging from 5 until 50 μm with VC addition.Keywords: aluminum bronze; niobium carbide; vanadium carbide; high energy ball milling; powder metallurgy.
Alexandre Nogueira Ottoboni Dias
Stainless steel components produced by powder metallurgy constitute an important and growing segment of the industry. The high energy ball milling process can be an alternative for the recycling of the stainless steel chips. A major advantage of stainless steel is its ability to be recyclable. The reuse of recyclable materials has as main objectives to minimize the environmental impacts and to rationalize the use of the energy chains. This work aims at the production of stainless steel, starting from machining chips pure, and with the addition of vanadium carbides by high energy planetary milling with ball to powder weight ratio 20:1, and mill speed of 350 rpm milled in argon atmosphere for 50h. The compaction of stainless steel samples with vanadium carbide was made in a cylindrical matrix at a pressure of 700 Mpa. The sintering process was performed in a vacuum atmosphere furnace at a temperature of 1200 ° C for 1h. Through the milling process with the addition of carbide it was possible to produce stainless steel powder with a mean particle size of 49 μm. By X-ray diffraction was observed the appearance of the ferritic, austenitic phase and the martensitic phase induced by deformation phase that remained even after the sintering. The density of the sintered material is around 77% of the melt, and the obtained porosity was low.
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