The movement of dislocations in a crystal is the key mechanism for plastic deformation in all materials. Studies of dislocations have focused on three-dimensional materials, and there is little experimental evidence regarding the dynamics of dislocations and their impact at the atomic level on the lattice structure of graphene. We studied the dynamics of dislocation pairs in graphene, recorded with single-atom sensitivity. We examined stepwise dislocation movement along the zig-zag lattice direction mediated either by a single bond rotation or through the loss of two carbon atoms. The strain fields were determined, showing how dislocations deform graphene by elongation and compression of C-C bonds, shear, and lattice rotations.
This paper presents a novel development of an ecological (eco) driving system for running a vehicle on roads with up-down slopes. Fuel consumed in a vehicle is greatly influenced by road gradients, aside from its velocity and acceleration characteristics. Therefore, optimum control inputs can only be computed through anticipated rigorous reasoning using information concerning road terrain, model of the vehicle dynamics, and fuel consumption characteristics. In this development, a nonlinear model predictive control method with a fast optimization algorithm is implemented to derive the vehicle control inputs based on road gradient conditions obtained from digital road maps. The fuel consumption model of a typical vehicle is formulated using engine efficiency characteristics and used in the objective function to ensure fuel economy driving. The proposed eco-driving system is simulated on a typical road with various shapes of up-down slopes. Simulation results reveal the ability of the eco-driving system in significantly reducing fuel consumption of a vehicle. The fuel saving behavior is graphically illustrated, compared, and analyzed to focus on the significance of this development.
Spatially resolved electron-energy-loss spectroscopy (EELS) is performed at diffuse interfaces between MoS2 and MoSe2 single layers. With a monochromated electron source (20 meV) we successfully probe excitons near the interface by obtaining the low loss spectra at the nanometer scale. The exciton maps clearly show variations even with a 10 nm separation between measurements; consequently, the optical band gap can be measured with nanometer-scale resolution, which is 50 times smaller than the wavelength of the emitted photons. By performing core-loss EELS at the same regions, we observe that variations in the excitonic signature follow the chemical composition. The exciton peaks are observed to be broader at interfaces and heterogeneous regions, possibly due to interface roughness and alloying effects. Moreover, we do not observe shifts of the exciton peak across the interface, possibly because the interface width is not much larger than the exciton Bohr radius.
We distinguish between Bernal and rhombohedral stacked trilayer graphene using aberration-corrected high-resolution transmission electron microscopy. By using a monochromator to reduce chromatic aberration effects, angstrom resolution can be achieved at an accelerating voltage of 80 kV, which enables the atomic structure of ABC rhombohedral trilayer graphene to be unambiguously resolved. Our images of ABC rhombohedral trilayer graphene provide a clear signature for its identification. Few-layer graphene interfaces with ABC:BC:BCAB structure have also been studied, and we have determined the stacking sequence of each graphene layer and consequently the 3D structure. These results confirm that CVD-grown few-layer graphene can adopt an ABC rhombohedral stacking.
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