In acetonitrile solution HOF oxides CF3SSCF3 via With CH3CN at low temperatures HOF and HF form 1 : 1 ad-CF3S(0),SCF3 (n = 1, 2) to yield [CF3S(0)2]20. Analogously, ducts, whose structures have been elucidated by low-tem-CF,Se(O)OH and CF,SeX (X= C1, Br) are oxidized via perature X-ray structure analysis. Additional proof for the CF,Se(VI) intermediates to provide finally [CF,Se(O),],O. formation of CH3CN . HF in the liquid phase is provided.
A skew structure with trans orientation of the two CF3 groups and with an OOOC dihedral angle of 96° describes the trioxide CF3OOOCF3 (see picture). The OO bond lengths are 1.452(5) (gas phase) and 1.437(2) Å (crystal).
Eine verdrillte Struktur mit trans‐ständigen CF3‐Gruppen und mit einem OOOC‐Diederwinkel von 96° hat das Trioxid CF3OOOCF3 in der Gasphase und im Kristall (Strukturbild rechts). Die O‐O‐Abstände wurden zu 1.452(5) und 1.437(2) Å (Gasphase bzw. Kristall) bestimmt.
ell. J. Phi.\ Chew 1985. 89. 3195-3197 R J Angelici. Inor,qiiti;< B i~~~~l t~~i t i t , \ /~ I . I b l 1. Elsevier. Amsterd,im. 1972 K.-D Scharl. S Kose. U' Zott. F Schdffl. L. N o \~r . E.NBO J 1990. 9. 44Y5 '1501 L. J Bclian:?. 71w Iir/,-urrd Spec I F N o/ C~o~r~p l v~ Molt( iilc,>, I ol 1 , Chapman and Hnll. London. 1975. R. Schrddcr. K L I I I I~~I I lulrurcd ,A/liis o/ Of,qittti( C o i r~p~i t t i~d~.
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