Synthesis methods of highly functional core@shell nanoparticles with high throughput and high purity are in great demand for applications, including catalysis and optoelectronics. Traditionally chemical synthesis has been widely explored,...
Earth-abundant transition
metal phosphides are promising materials
for energy-related applications. Specifically, copper(I) phosphide
is such a material and shows excellent photocatalytic activity. Currently,
there are substantial research efforts to synthesize well-defined
metal–semiconductor nanoparticle heterostructures to enhance
the photocatalytic performance by an efficient separation of charge
carriers. The involved crystal facets and heterointerfaces have a
major impact on the efficiency of a heterostructured photocatalyst,
which points out the importance of synthesizing potential photocatalysts
in a controlled manner and characterizing their structural and morphological
properties in detail. In this study, we investigated the interface
dynamics occurring around the synthesis of Ag–Cu3P nanoparticle heterostructures by a chemical reaction between Ag–Cu
nanoparticle heterostructures and phosphine in an environmental transmission
electron microscope. The major product of the Cu–Cu3P phase transformation using Ag–Cu nanoparticle heterostructures
with a defined interface as a template preserved the initially present
Ag{111} facet of the heterointerface. After the complete transformation,
corner truncation of the faceted Cu3P phase led to a physical
transformation of the nanoparticle heterostructure. In some cases,
the structural rearrangement toward an energetically more favorable
heterointerface has been observed and analyzed in detail at the atomic
level. The herein-reported results will help better understand dynamic
processes in Ag–Cu3P nanoparticle heterostructures
and enable facet-engineered surface and heterointerface design to
tailor their physical properties.
In the last decades, the metal‐assisted growth approach of semiconductor nanowires (NWs) has shown its potential in controlling crystal properties, such as crystal structure, composition, and morphology. Recently, literature reports have shown successful semiconductor NW growth with multiphase seed particles under growth conditions. Exploring alternative metal seeds and the mechanisms for growing semiconductor NWs is an exciting research field aiming to improve the control over the crystal growth process. Herein, the gallium phosphide (GaP) NW growth using Cu as seed particles inside an environmental transmission electron microscope is studied. In particular, the transformations of the Cu‐rich seed particles during the nucleation and growth of GaP NWs are observed. The supply of a relatively high amount of Ga atoms by the precursor mixture led to a solid Cu‐rich seed particle core covered by a liquid phase. Different growth dynamics within the two‐phase seed particle resulted in local competition in NW growth. As a result, the GaP NW kinked into another growth direction by forming a new interface at the NW growth front. The generated results enable insights into fundamental processes occurring in the seed particle during growth, creating leverage points for controlling the NW morphology.
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