Room-temperature ferromagnetism was observed in undoped and Fe2+(3+)-doped CeO2 nanocrystals. In Fe-doped samples the enhancement of ferromagnetic ordering occurs by changing the valence state of Fe ions, whereas Raman spectra demonstrated strong electron-molecular vibrational coupling and increase in oxygen vacancy concentration. Air annealing showed degradation of ferromagnetic ordering and appearance of hematite phase in Fe3+-doped sample. The observed ferromagnetic coupling in Fe-doped samples, associated with the presence of magnetic ions mediated by single charged O2− vacancies, demonstrated that valence state of dopant has a strong influence on magnetic properties of CeO2 nanoparticles.
We present a symmetry analysis of allowed infrared and Raman modes in graphene and highly oriented pyrolytic graphite. Surface structure for highly oriented pyrolytic graphite is examined using atomic force microscopy. As experimental tools, we used infrared spectroscopic ellipsometry in order to investigate the pseudodielectric function of highly oriented pyrolytic graphite in the mid-infrared range (500-7000 cm −1 ) and Raman spectroscopy to investigate the influence of layers number decrease. As a result, we propose a method for an experimental verification of graphene.
Raman spectra of Nd doped ceria nanocrystals were measured by gradual heating and cooling over the temperature range of 293–1073K and analyzed using the phonon confinement model that incorporates inhomogeneous strain and anharmonic effects. We have demonstrated that in nanograins, four-phonon anharmonic processes are more dominant at higher temperatures than size effects. After the heat treatment, Nd doped ceria nanocrystals remain of nanometric range (∼20nm) while the concentration of oxygen vacancies is still high in ceria lattice, making this material convenient for solid oxide fuel cells application.
Recently,
multifunctional devices printed on flexible substrates, with multisensing
capability, have found new demand in practical fields of application,
such as wearable electronics, soft robotics, interactive interfaces,
and electronic skin design, revealing the vital importance of precise
control of the fundamental properties of metal oxide nanomaterials.
In this paper, a novel low-cost and scalable processing strategy is
proposed to fabricate all-printed multisensing devices with UV- and
gas-sensing capabilities. This undertaken approach is based on the
hierarchical combination of the screen-printing process and laser
irradiation post-treatment. The screen-printing is used for the patterning
of silver interdigitated electrodes and the active layer based on
anatase TiO2 nanoparticles, whereas the laser processing
is utilized to fine-tune the UV and ethanol-sensing properties of
the active layer. Different characterization techniques demonstrate
that the laser fluence can be adjusted to optimize the morphology
of the TiO2 film by increasing the contribution from volume
porosity, to improve its electrical properties and enhance its UV
photoresponse and ethanol-sensing characteristics at room temperature.
Furthermore, results of the UV and ethanol-sensing investigation show
that the optimized UV and ethanol sensors have good repeatability,
relatively fast response/recovery times, and excellent mechanical
flexibility.
Electrochemical biosensors utilizing nanomaterials have received widespread attention in pathogen detection and monitoring. Here, the potential of different nanomaterials and electrochemical technologies is reviewed for the development of novel diagnostic devices for the detection of foodborne pathogens and their biomarkers. The overview covers basic electrochemical methods and means for electrode functionalization, utilization of nanomaterials that include quantum dots, gold, silver and magnetic nanoparticles, carbon nanomaterials (carbon and graphene quantum dots, carbon nanotubes, graphene and reduced graphene oxide, graphene nanoplatelets, laser-induced graphene), metal oxides (nanoparticles, 2D and 3D nanostructures) and other 2D nanomaterials. Moreover, the current and future landscape of synergic effects of nanocomposites combining different nanomaterials is provided to illustrate how the limitations of traditional technologies can be overcome to design rapid, ultrasensitive, specific and affordable biosensors.
This paper describes the fabrication and the characterization of an original example of a miniaturized resistive-type humidity sensor, printed on flexible substrate in a large-scale manner. The fabrication process involves laser ablation for the design of interdigitated electrodes on PET (Poly-Ethylene Terephthalate) substrate and a screen-printing process for the deposition of the sensitive material, which is based on TiO2 nanoparticles. The laser ablation process was carefully optimized to obtain micro-scale and well-resolved electrodes on PET substrate. A functional paste based on cellulose was prepared in order to allow the precise screen-printing of the TiO2 nanoparticles as sensing material on the top of the electrodes. The current against voltage (I–V) characteristic of the sensor showed good linearity and potential for low-power operation. The results of a humidity-sensing investigation and mechanical testing showed that the fabricated miniaturized sensors have excellent mechanical stability, sensing characteristics, good repeatability, and relatively fast response/recovery times operating at room temperature.
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