Groundwater is the largest available store of global freshwater , upon which more than two billion people rely 2. It is therefore important to quantify the spatiotemporal interactions between groundwater and climate. However, current understanding of the global scale sensitivity of groundwater systems to climate change 3,4-as well as the resulting variation in feedbacks from groundwater to the climate system 5,6-is limited. Here, using groundwater model results in combination with hydrologic datasets, we examine the dynamic timescales of groundwater system responses to climate change. We show that nearly half of global groundwater fluxes could equilibrate with recharge variations due to climate change on human (~100 year) timescales, and that areas where water tables are most sensitive to changes in recharge are also those that have the longest groundwater response times. In particular, groundwater fluxes in arid regions are shown to be less responsive to climate variability than in humid regions. Adaptation strategies must therefore account for the hydraulic memory of groundwater systems which can buffer climate change impacts on water resources in many regions, but may also lead to a long, but initially hidden, legacy of anthropogenic and climatic impacts on river flows and groundwater dependent ecosystems.

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Groundwater in Africa supports livelihoods and poverty alleviation 1,2 , maintains vital ecosystems, and strongly influences terrestrial water and energy budgets 3. However, hydrologic processes governing groundwater recharge sustaining this resource, and their sensitivity to climatic variability, are poorly constrained 4,5. Here we show, through analysis of multi-decadal groundwater hydrographs across sub-Saharan Africa, how aridity controls the predominant recharge processes whereas local hydrogeology influences the type and sensitivity of precipitation-recharge relationships. Some humid locations show approximately linear precipitation-recharge relationships with small rainfall intensity exceedance thresholds governing recharge; others show surprisingly small variation in recharge across a wide range of annual precipitation. As aridity increases, precipitation thresholds governing initiation of recharge increase, recharge becomes more episodic, and focussed recharge via losses from ephemeral overland flows becomes increasingly dominant. Extreme annual recharge is commonly associated with intense rainfall and flooding events, themselves often driven by largescale climate controls. Intense precipitation, even during lower precipitation years, produces substantial recharge in some dry subtropical locations, challenging the 'high certainty' consensus that drying climatic trends will decrease water resources in such regions 4. The likely resilience of groundwater in many areas revealed by improved understanding of precipitation-recharge

The groundwater hydraulic head response to the worldwide and ubiquitous atmospheric tide at 2 cycles per day (cpd) is a direct function of confined aquifer compressible storage. The ratio of the responses of hydraulic head to the atmospheric pressure change is a measure of aquifer barometric efficiency, from which formation compressibility and aquifer specific storage can be determined in situ rather than resorting to laboratory or aquifer pumping tests. The Earth tide also impacts the hydraulic head response at the same frequency, and a method is developed here to quantify and remove this interference. As a result, the barometric efficiency can be routinely calculated from 6‐hourly hydraulic head, atmospheric pressure, and modeled Earth tide records where available for a minimum of 15 days duration. This new approach will be of critical importance in assessing worldwide problems of land subsidence or groundwater resource evaluation that both occur due to groundwater abstraction.

Groundwater is a crucial resource for current and future generations, but it is not being sustainably used in many parts of the world. The objective of this review is to provide a clear portrait of global-scale groundwater sustainability, systems, and resources in the Anthropocene to inspire a pivot toward more sustainable pathways of groundwater use. We examine groundwater from three different but related perspectives of sustainability science, natural resource governance and management, and Earth System science. An Earth System approach highlights the connections between groundwater and the other parts of the system and how these connections are impacting, or are impacted by, groundwater pumping. Groundwater is the largest store of unfrozen freshwater on Earth and is heterogeneously connected to many Earth System processes on different timescales. We propose a definition of groundwater sustainability that has a direct link with observable data, governance, and management as well as the crucial functions and services of groundwater. ▪  Groundwater is depleted or contaminated in some regions; it is ubiquitously distributed, which, importantly, makes it broadly accessible but also slow and invisible and therefore challenging to govern and manage. ▪  Regional differences in priorities, hydrology, politics, culture, and economic contexts mean that different governance and management tools are important, but a global perspective can support higher level international policies in an increasingly globalized world that require broader analysis of interconnections and knowledge transfer between regions. ▪  A coherent, overarching framework of groundwater sustainability is more important for groundwater governance and management than the concepts of safe yield, renewability, depletion, or stress.

Microbially induced calcite precipitation (MICP) offers an attractive alternative to traditional grouting technologies for creating barriers to groundwater flow and containing subsurface contamination, but has only thus far been successfully demonstrated at the laboratory scale and predominantly in porous media. We present results of the first field experiments applying MICP to reduce fractured rock permeability in the subsurface. Initially, the ureolytic bacterium, Sporosarcina pasteurii, was fixed in the fractured rock. Subsequent injection of cementing fluid comprising calcium chloride and urea resulted in precipitation of large quantities (approximately 750 g) of calcite; significant reduction in the transmissivity of a single fracture over an area of several m(2) was achieved in around 17 h of treatment. A novel numerical model is also presented which simulates the field data well by coupling flow and bacterial and solute reactive transport processes including feedback due to aperture reduction via calcite precipitation. The results show that MICP can be successfully manipulated under field conditions to reduce the permeability of fractured rock and suggest that an MICP-based technique, informed by numerical models, may form the basis of viable solutions to aid pollution mitigation.

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