We report on highly stretchable piezoelectric structures of electrospun PVDF-TrFE nanofibers. We fabricated nanofibrous PVDF-TrFE yarns via twisting their electrospun ribbons. Our results show that the twisting process not only increases the failure strain but also increases overall strength and toughness. The nanofibrous yarns achieved a remarkable energy to failure of up to 98 J/g. Through overtwisting process, we fabricated polymeric coils out of twisted yarns that stretched up to ∼740% strain. This enhancement in mechanical properties is likely induced by increased interactions between nanofibers, contributed by friction and van der Waals interactions, as well as favorable surface charge (Columbic) interactions as a result of piezoelectric effect, for which we present a theoretical model. The fabricated yarns and coils show great promise for applications in high-performance lightweight structural materials and superstretchable piezoelectric devices and flexible energy harvesting applications.
High performance piezoelectric devices based on arrays of PVDF-TrFE nanofibers have been introduced in the literature for a variety of applications including energy harvesting and sensing. In this Research Article, we utilize uniaxial tensile test on arrays of nanofibers, microtensile, and nanoindentation and piezo-response force microscopy (PFM) on individual nanofibers, as wells as DSC, XRD, and FTIR spectroscopy to investigate the effect of annealing on microstructure, mechanical, and piezoelectric properties of arrays and individual electrospun nanofibers. For PVDF-TrFE nanofibers annealing in a temperature between the Curie and melting temperature (in paraelectric phase) results in ∼70% increase in crystallinity of the nanofibers. The findings of our multiscale experiments reveal that this improvement in crystallinity results in ∼3-fold increase in elastic modulus, and ∼55% improvement in piezoelectric constant. Meanwhile, the ductility and tensile toughness of the nanofibers drop by ∼1 order of magnitude. In addition, nanoscale cracks were observed on the surface of the annealed nanofibers; however, they did not result in significant change in the strength of the nanofibers. The results of this work may have important implications for applications of PVDF-TrFE in energy harvesting, biomedical, and sensor areas.
Smart textiles are envisioned to make a paradigm shift in wearable technologies to directly impart functionality into the fibers rather than integrating sensors and electronics onto conformal substrates or skin in wearable devices. Among smart materials, piezoelectric fabrics have not been widely reported, yet. Piezoelectric smart fabrics can be used for mechanical energy harvesting, for thermal energy harvesting through the pyroelectric effect, for ferroelectric applications, as pressure and force sensors, for motion detection, and for ultrasonic sensing. We report on mechanical and material properties of the plied nanofibrous piezoelectric yarns as a function of postprocessing conditions including thermal annealing and drawing (stretching). In addition, we used a continuous electrospinning setup to directly produce P(VDF-TrFE) nanofibers and convert them into twisted plied yarns, and demonstrated application of these plied yarns in woven piezoelectric fabrics. The results of this work can be an early step toward realization of piezoelectric smart fabrics.
Collagen, which is the most abundant protein in mammals, is demonstrated as a substrate for flexible implantable electronics. Using electron beam deposition, devices are fabricated on transparent collagen type I films. Several applications, including a strain gauge, a wireless antenna, a heater, and a temperature sensor, are demonstrated, showcasing the promising future applications of this substrate for implantable biomedical devices for monitoring of physiological environment.
Nanotwinned (nt)-metals exhibit superior mechanical and electrical properties compared to their coarse-grained and nanograined counterparts. nt-metals in film and bulk forms are obtained using physical and chemical processes including pulsed electrodeposition (PED), plastic deformation, recrystallization, phase transformation, and sputter deposition. However, currently, there is no process for 3D printing (additive manufacturing) of nt-metals. Microscale 3D printing of nt-Cu is demonstrated with high density of coherent twin boundaries using a new room temperature process based on localized PED (L-PED). The 3D printed nt-Cu is fully dense, with low to none impurities, and low microstructural defects, and without obvious interface between printed layers, which overall result in good mechanical and electrical properties, without any postprocessing steps. The L-PED process enables direct 3D printing of layer-by-layer and complex 3D microscale nt-Cu structures, which may find applications for fabrication of metamaterials, sensors, plasmonics, and micro/nanoelectromechanical systems.
We report on the synthesis and the mechanical characterization of an alginate-collagen fibril composite hydrogel. Native type I collagen fibrils were used to synthesize the fibrous composite hydrogel. We characterized the mechanical properties of the fabricated fibrous hydrogel using tensile testing; rheometry and atomic force microscope (AFM)-based nanoindentation experiments. The results show that addition of type I collagen fibrils improves the rheological and indentation properties of the hydrogel.
Nanotwinned-metals (nt-metals) offer superior mechanical (high ductility and strength) and electrical (low electromigration) properties compared to their nanocrystalline (nc) counterparts. These properties are advantageous in particular for applications in nanoscale devices. However, fabrication of nt-metals has been limited to films (two-dimensional) or template-based (one-dimensional) geometries, using various chemical and physical processes. In this Letter, we demonstrate the ambient environment localized pulsed electrodeposition process for direct printing of three-dimensional (3D) freestanding nanotwinned-Copper (nt-Cu) nanostructures. 3D nt-Cu structures were additively manufactured using pulsed electrodeposition at the tip of an electrolyte-containing nozzle. Focused ion beam (FIB) and transmission electron microscopy (TEM) analysis revealed that the printed metal was fully dense, and was mostly devoid of impurities and microstructural defects. FIB and TEM images also revealed nanocrystalline-nanotwinned-microstructure (nc-nt-microstructure), and confirmed the formation of coherent twin boundaries in the 3D-printed Cu. Mechanical properties of the 3D-printed nc-nt-Cu were characterized by direct printing (FIB-less) of micropillars for in situ SEM microcompression experiments. The 3D-printed nc-nt-Cu exhibited a flow stress of over 960 MPa, among the highest ever reported, which is remarkable for a 3D-printed material. The microstructure and mechanical properties of the nc-nt-Cu were compared to those of nc-Cu printed using the same process under direct current (DC) voltage.
Meniscus-confined electrodeposition (MCED) is a solution-based, room temperature process for 3D printing of metals at micro/nanoscale. In this process, a meniscus (liquid bridge or capillary) between a nozzle and a substrate governs the localized electrodeposition process, which involves multiple physics of electrodeposition, fluid dynamics, mass, and heat transfer. We have developed a multiphysics finite element (FE) model to investigate the effects of nozzle speed (vN) and nozzle diameter (D0) in the MCED process. The simulation results are validated with experimental data. Based on theoretical approach and experimental observation, the diameter of the deposited wire is in the range of 0.5–0.9 times of the nozzle diameter. The applicable range for vN for various nozzle diameters is computed. The results showed that the contribution of migration flux to total flux remains nearly constant (∼50%) for all values of pipette diameter in the range examined (100 nm–5 μm), whereas the contribution of diffusion and evaporation fluxes to total flux increase and decrease with the increasing pipette diameter, respectively. Results of this multiphysics study can be used to guide the experiment for optimal process conditions.
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