In stitu t für A norganische Chem ie d er U n iversität S tu ttg art, P faffenw aldring 55, D-7000 S tu ttg art 80 Axel Obermeyer M ax -P lanck-Institut für F estkörperforschung, H eisenbergstraße 1, D-7000 S tu ttg a rt 80 Herrn Prof. Dr. Kurt Dehnicke zum 60. Geburtstag gewidm et Z. N aturforsch. 46b, 4 5 9 -4 6 7 (1991); eingegangen am 11. S eptem ber 1990 Z inn-und Indium -bis(trim ethylsilyl)am ide, B is(trim ethylsilyl)am ides, X -R ay, IR Spectra, R am an Spectra, N M R Spectra B rSn[N (SiM e3)2]3 and C lIn[N (SiM e3)2]2 react w ith L iM e O ( C 2H 5)2 (M e = C H 3) in toluene or hexane to give the co rresponding am ido derivatives M eM [N (S iM e3)2]v (M = Sn, x = 3 and M = In, x = 2). These new co m p o u n d s an d the o th e r m em bers o f the h o m o lo g o u s series M e"M [N (SiM e3)2]4 or 3_" are characterized by their IR . R am an und N M R spectra. In addition, the results o f the crystal structure determ in atio n o f M eS n[N (S iM e3)2]3 are reported.
Methyltin and Methylindium Bis(trimethylsilyl)amides.-In order to characterize the complete homologous series of amido compounds by IR and Raman spectra, the two missing members (III) and ( VI) are prepared by methylation of the corresponding bromo or chloro derivatives. -(RANNENBERG, M.; WEIDLEIN, J.; OBERMEYER, A.; Z. Naturforsch., B: Chem. Sci. 46 (1991) 4, 459-467; Inst. Anorg. Chem., Univ. Stuttgart, W-7000 Stuttart 80, Fed. Rep. Ger.; DE)
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