Si nanocrystals (Si-NCs) dispersible in polar liquid without surface functionalization by organic molecules have been realized by simultaneously doping n and p type impurities. We show that the codoped Si-NCs are stable in methanol for more than five months, while intrinsic Si-NCs prepared by the same procedure form large agglomerates. The different behavior of the intrinsic and codoped Si-NCs in solutions suggests that doped impurities exist on the surface of Si-NCs and the surface potential is large enough to prevent the agglomeration. The colloidal solution of codoped Si-NCs exhibits broad photoluminescence with the maximum in the near infrared range (1.1-1.3 eV).
Nanometer-scale Si quantum dots have been spontaneously fabricated on SiO2 by controlling the early stages of low-pressure chemical vapor deposition from pure silane. The tunneling current through Au/1 nm-SiO2/a single Si quantum dot/1 nm-SiO2/n+-Si(100) double-barrier structures has exhibited the clear current bump or negative conductance at 300 K with a peak current to valley ratio as high as 10.
Boron (B) doped Si nanocrystals (Si-ncs) dispersed in hydrofluoric (HF) acid solution are prepared by dissolving borosilicate films containing B-doped Si-ncs in HF solution. We find that the etching rate of B-doped Si-ncs is much smaller than that of undoped Si-ncs. The difference of the etching rate allows us to extract only doped Si-ncs in the mixture of doped and undoped Si-ncs and observe the photoluminescence (PL) due to the transition from the conduction band to the acceptor state. The PL was very broad with the maximum around 1.15 eV. From the analysis of the PL data obtained for the samples prepared under different conditions and different etching time, preferential doping sites of B atoms are estimated. The data suggests that B-doped Si-ncs consists of intrinsic cores and heavily B-doped shells. V
A comprehensive analysis of gened relativistic spacetimes which admit a shearfree, irrotational and geodesic time-like coogruence is presented. The equations governing the models for a gened energy-momentum tensor are wrilten down. Coordinates in which the metric of such spacetimes takes on a simplified form are established. The general subwses of 'zero anisotropic stress', 'zero heat-flux vector' and 'two-component Ruids' are investigated. In particular, perfect-fluid Friedmann-Robertson-Walker models and spatially homogeneous models are discussed. Models with a variety of physically relevant energy-momentum tensors are considered. Anisowopic fluid models and viscous fluid models with heat conduction are examined. Also. models with B perfect Ruid plus a magnetic field or with pure radiation. and models with two non-collinw perfect fluids (satisfying a variety of physical conditions) are inwtigated. In particular. models with a (single) perfect Ruid which is tilting with respect to the shem-free, vorticity-free and acceleration-free time-like congruence are discussed.PACS numbers: 0420J. 9880H
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