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Cyclic voltammetry, chronoamperometry and FTIR-ATR techniques were used to investigate the phenol electropolymerization on carbon steel and stainless steel electrodes in carbonate aqueous medium. Phenol electropolymerization occurs on a passivated surface and the polymer grows to thickness of 0.1 to 0.2 µ m. Polymeric films are adherent and stables under ambient conditions. The polymeric film maintains aromatic character and contains etherlinked rings.

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