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This article presents the results of a round-robin test performed by 13 international research groups in the framework of the activities of the RILEM Technical Committee 260 RSC "Recommendations for use of superabsorbent polymers in concrete construction". Two commercially available superabsorbent polymers (SAP) with different chemical compositions and gradings were tested in terms of their kinetics of absorption in different media; demineralized water, cement filtrate solution with particular cement distributed to every participant and local cement chosen by the participant. Two absorption test methods were 2 considered; the tea-bag method and the filtration method. The absorption capacity was evaluated as a function of time. The results showed correspondence in behaviour of the SAPs among all participants, but also between the two test methods, even though high scatter was observed at early minutes of testing after immersion. The tea-bag method proved to be more practical in terms of time dependent study, whereby the filtration method showed less variation in the absorption capacity after 24 hours. However, absorption followed by intrinsic, ion-mediated desorption of a respective SAP sample in the course of time was not found by the filtration method. This SAP-specific characteristic was only displayed by the teabag method. This demonstrates the practical applicability of both test methods, each one having their own strengths and weaknesses at distinct testing times.

Conventionally, isothermal calorimetry and ASTM C186 heat of hydration results are reported on a per mass of cement (powder) basis, with typical units being J/g (cement) for example. Based on the recognition that it is the filling of porosity with hydration products that is chiefly responsible for strength development in cement-based materials, there may be merit in instead reporting these results on a per unit volume of (initial) water basis. This paper examines a database of well over 200 mortar mixtures to investigate the relationship between heat release and mortar cube compressive strength development. For reasonably low water-to-cementitious materials ratios (w/cm < 0.43), a single universal straight line relationship with some scatter is obtained. Based on numerous experimental data sets and accompanying theoretical computations, the effects of w/cm, sand volume fraction, cement chemical composition, sulfate content, cement fineness, the incorporation of a high range water reducing admixture, and curing conditions on this universal relationship are all considered. Fifty data points from the Cement and Concrete Reference Laboratory (CCRL) proficiency sample program are analyzed to develop a linear relationship between ASTM C109 mortar cube compressive strengths and ASTM C186 heats of hydration at 7 d and 28 d. The application of this relationship for virtual testing is also evaluated. In this case, computer simulations would be employed to predict the heat of hydration vs. time for a particular cement and the developed equations would be employed to convert this heat release to a strength prediction at the age(s) of interest. In general, it appears that these relationships can be used to predict mortar cube compressive strengths based on measured heats of hydration, within about ± 10 % of the experimentally measured strengths. A preliminary analysis of a single dataset for concretes with and without limestone replacement for cement indicates that the linear relationship between strength and heat release likely holds for concretes as well as mortars.

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Bond between two cementitious materials is crucial in applications such as repairs, overlays, and connections of prefabricated bridge elements (PBEs), to name just a few. It is the latter that has special interest to the authors of this paper. After performing a dimensional stability study on grout-like materials commonly used as connections between PBEs, it was observed that the so-called 'non-shrink' cementitious grouts showed a considerable amount of early-age shrinkage. This might have negative effects on the integrity of the structure, due not only to the grout material's early degradation, but also to a possible loss of bond between the grout and the prefabricated concrete element. Many factors affect the bond strength between two cementitious materials (e.g., grout-concrete), the presence of moisture at the existing concrete substrate surface being one of them. In this regard, pre-moistening the concrete substrate surface prior to the application of the grout material is sometimes recommended for bond enhancement. This topic has been the focus of numerous research studies in the past; however, there is still controversy among practitioners on the real benefits that this practice might provide. This paper evaluates the tensile bond performance of two non-shrink cementitious grouts applied to the exposed aggregate surface of a concrete substrate, and how the supply of moisture at the grout-concrete interface affects the bond strength. "Pull-off" bond results show increased tensile bond strength when the concrete surface is pre-moistened. Reasons to explain the observed increased bond strength are given after a careful microstructural analysis of the grout-concrete interface. Interfaces where sufficient moisture is provided to the concrete substrate such that moisture movement from the grout is prevented show reduced porosity and increased hydration on the grout side of the interface, which is thought to directly contribute to the increased tensile bond strength.

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There are conflicting views in the literature concerning the optimum moisture state for an existing substrate prior to the application of a repair material. Both saturated-surface-dry (SSD) and dry substrates have been found to be preferable in a variety of studies. One confounding factor is that some studies evaluate bonding of the repair material to the substrate via pull-off (direct tension) testing, while others have employed some form of shear specimens as their preferred testing configuration. Available evidence suggests that dry substrate specimens usually perform equivalently or better in shear testing, while SSD ones generally exhibit higher bond strengths when a pull-off test is performed, although exceptions to these trends have been observed. This paper applies a variety of microstructural characterization tools to investigate the interfacial microstructure that develops when a fresh repair material is applied to either a dry or SSD substrate. Simultaneous neutron and X-ray radiography are employed to observe the dynamic microstructural rearrangements that occur at this interface during the first 4 h of curing. Based on the differences in water movement and densification (particle compaction) that occur for the dry and SSD specimens, respectively, a hypothesis is formulated as to why different bond tests may favor one moisture state over the other, also dependent on their surface roughness. It is suggested that the compaction of particles at a dry substrate surface may increase the frictional resistance when tested under slant shear loading, but contribute relatively little to the bonding when the interface is submitted to pull-off forces. For maximizing bond performance, the fluidity of the repair material and the roughness and moisture state of the substrate must all be given adequate consideration.

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