The hydrogen diffusion in welding was investigated by using thermal-mechanical-hydrogen diffusion sequential coupled procedures based on finite element method. A self-gathering effect induced by the solid-state phase transformation was discovered. Because of the self-gathering effect, the hydrogen concentration in weld metal was accumulated to a peak value which can be larger than the initial hydrogen concentration in molten pool, and subsequently the hydrogen concentration in heat affect zone was redistributed. In multi-pass welding, the gathered effect not only happened inside a weld pass, but also in the inter-pass, which further increased the sensitivity of the hydrogen-assisted cold cracking. Controlling should be adopted to restrain the hydrogen accumulation. Welding stress evolution during the solid-state phase transformation process had limited effect on the hydrogen diffusion.
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