A theoretical model is derived to account for the deuterium-oxygen 18 relationship measured in meteoric waters. A steady state regime is assumed for the evaporation of water at the ocean surface and the subsequent formation of precipitation. The calculations show that the deuterium and oxygen 18 content in precipitation can be taken as linearly related. From the slope and the intercept (known as the deuterium excess) of the bD-b•80 linear relationship for precipitation we compute the mean values on a global scale of the evaporating ocean surface temperature and the relative humidity of the air masses overlying the oceans. The deuterium excess is primarly dependent on the mean relative humidity of the air masses formed above the ocean surface. Paleoclimatic data may be obtained by this isotopic method from the analysis of old water and ice samples. A moisture deficit of the air over the ocean, equal to only 10%, in comparison to 20% for modern conditions, is deduced from the deuterium-oxygen 18 distribution measured in groundwater samples older than 20,000 years. the value of T, = 25.4øC (-1-2.2 ø) that we have derived.We have no direct way to discuss the value of h. The isotopic method does not allow us to draw conclusions about the (Received December 19, 1978; aerodynamic regime at the ocean surface because the kinetic revised April 5, 1979; fractionation factors depend only very weakly on the wind

Turbulence structure and mass transfer across a sheared air-water interface in wind-driven turbulence,

The classical Rayleigh model assuming isotopic equilibrium fails to explain the deuterium and oxygen 18 contents of polar snow. This model leads to too high temperature‐isotope gradients (both for δD and δ18O), to too low δD ‐ δ18O slopes, and consequently to an excessively large range of deuterium excess values (d = δD ‐ 8δ18O). We present a new model that takes into account the existence of an isotopic kinetic effect at snow formation as a result of the fact that vapor deposition occurs in an environment supersaturated over ice. This kinetic effect is thoroughly discussed from a microphysical point of view and tested against experimental data and field observations. This new formulation reconciles predicted and observed values both for the temperature‐isotope and δD ‐ δD18O relationships for reasonable values of supersaturation over ice.

A new feature is the data set quality control (QC) flag of E for data from alternative sensors and platforms. The accuracy of surface water f CO 2 has been defined for all data set QC flags. Automated range checking has been carried out for all data sets during their upload into SOCAT. The upgrade of the interactive Data Set Viewer (previously known as the Cruise Data Viewer) allows better interrogation of the SOCAT data collection and rapid creation of high-quality figures for scientific presentations. Automated data upload has been launched for version 4 and will enable more frequent SOCAT releases in the future. Highprofile scientific applications of SOCAT include quantification of the ocean sink for atmospheric carbon dioxide and its long-term variation, detection of ocean acidification, as well as evaluation of coupled-climate and ocean-only biogeochemical models. Users of SOCAT data products are urged to acknowledge the contribution of data providers, as stated in the SOCAT Fair Data Use Statement. This ESSD (Earth System Science Data) "living data" publication documents the methods and data sets used for the assembly of this new version of the SOCAT data collection and compares these with those used for earlier versions of the data collection Sabine et al., 2013;Bakker et al., 2014). Individual data set files, included in the synthesis product, can be downloaded here: doi:10.1594/PANGAEA.849770. The gridded products are available here: