The increasing concern for safety and sustainability of structures is calling for the development of smart self-healing materials and preventive repair methods. The appearance of small cracks (<300 µm in width) in concrete is almost unavoidable, not necessarily causing a risk of collapse for the structure, but surely impairing its functionality, accelerating its degradation, and diminishing its service life and sustainability. This review provides the state-ofthe-art of recent developments of self-healing concrete, covering autogenous or intrinsic healing of traditional concrete followed by stimulated autogenous healing via use of mineral additives, crystalline admixtures or (superabsorbent) polymers, and subsequently autonomous self-healing mechanisms, i.e. via, application of micro-, macro-, or vascular encapsulated polymers, minerals, or bacteria. The (stimulated) autogenous mechanisms are generally limited to healing crack widths of about 100-150 µm. In contrast, most autonomous self-healing mechanisms can heal cracks of 300 µm, even sometimes up to more than 1 mm, and usually act faster. After explaining the basic concept for each self-healing technique, the most recent advances are collected, explaining the progress and current limitations, to provide insights toward the future developments. This review addresses the research needs required to remove hindrances that limit market penetration of self-healing concrete technologies.

The aim of this study is analyzing the self-healing effect of a crystalline admixture in four types of 11 environmental exposure comparing with a reference concrete. Healing was studied by means of permeability tests on 12 cracked specimens and physical closing of the crack was observed by optic microscope and quantified through crack 13 geometrical parameters. The studied crack openings were under 300 μm and the time set for healing was 42 days. The 14 results show a different healing behavior depending on the exposure and the presence of the crystalline admixture, 15 demonstrating that the presence of water is necessary for the healing reactions. 16

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This paper analyzes the self-healing properties of early-age concretes, engineered using a crystalline admixture (4% by the weight of cement), by measuring the permeability of cracked specimens and their crack width. Two concrete classes (C30/37 and C45/55) and three healing exposure conditions have been investigated: water immersion at 15 °C, at 30 °C and wet/dry cycles. Specimens were pre-cracked at 2 days, to values of crack width in the range of 0.10–0.40 mm. The results show almost perfect healing capability for specimens healed under water at 30 °C, better than for specimens healed under water at 15 °C, while insufficient for the wet/dry exposure

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Calcium metabolism has been investigated in patients with essential hypertension and normal renal function to evaluate the renal calcium handling and the reported increase in renal calcium loss. In 55 hypertensive and 55 sex- and age-matched healthy normotensive subjects creatinine clearance, serum total and ionized calcium, plasma parathyroid hormone and 24 h urinary excretion of calcium, sodium and cAMP were measured. In a subgroup of 20 hypertensive patients and 20 controls the fasting calcium excretion rate was also measured. Both 24 h and fasting calcium excretion rates were higher in the hypertensive group; so also were plasma parathyroid hormone and urinary cAMP. Serum total and ionized calcium levels were not different in the two groups. After intravenous calcium infusion (15 mg 3 h-1 kg-1) in seven hypertensive patients and controls, the hypertensive patients excreted more calcium at all serum calcium concentrations. These results support the hypothesis of primary renal calcium leak in essential hypertension. Enhanced urinary calcium excretion rate may cause compensatory parathyroid overactivity.