We report the creation of a nanoscale electrochemical device inside a transmission electron microscope--consisting of a single tin dioxide (SnO(2)) nanowire anode, an ionic liquid electrolyte, and a bulk lithium cobalt dioxide (LiCoO(2)) cathode--and the in situ observation of the lithiation of the SnO(2) nanowire during electrochemical charging. Upon charging, a reaction front propagated progressively along the nanowire, causing the nanowire to swell, elongate, and spiral. The reaction front is a "Medusa zone" containing a high density of mobile dislocations, which are continuously nucleated and absorbed at the moving front. This dislocation cloud indicates large in-plane misfit stresses and is a structural precursor to electrochemically driven solid-state amorphization. Because lithiation-induced volume expansion, plasticity, and pulverization of electrode materials are the major mechanical effects that plague the performance and lifetime of high-capacity anodes in lithium-ion batteries, our observations provide important mechanistic insight for the design of advanced batteries.
Atomically dispersed noble metal
catalysts have drawn wide attention
as candidates to replace supported metal clusters and metal nanoparticles.
Atomic dispersion can offer unique chemical properties as well as
maximum utilization of the expensive metals. Addition of a second
metal has been found to help reduce the size of Pt ensembles in bimetallic
clusters; however, the stabilization of isolated Pt atoms in small
nests of nonprecious metal atoms remains challenging. We now report
a novel strategy for the design, synthesis, and characterization of
a zeolite-supported propane dehydrogenation catalyst that incorporates
predominantly isolated Pt atoms stably bonded within nests of Zn atoms
located within the nanoscale pores of dealuminated zeolite Beta. The
catalyst is stable in long-term operation and exhibits high activity
and high selectivity to propene. Atomic resolution images, bolstered
by X-ray absorption spectra, demonstrate predominantly atomic dispersion
of the Pt in the nests and, with complementary infrared and nuclear
magnetic resonance spectra, determine a structural model of the nested
Pt.
We have revealed the fundamental embryonic structure of deformation twins using in situ mechanical testing of magnesium single crystals in a transmission electron microscope. This structure consists of an array of twin-related laths on the scale of several nanometers. A computational model demonstrates that this structure should be a generic feature at the incipient stage of deformation twinning when there are correlated nucleation events. Our results shed light on the origin of twinning-induced plasticity and transformation toughening, critical to the development of advanced structural alloys with high strength, ductility, and toughness.
Two-dimensional atomic sheets such as graphene and boron nitride monolayers represent a new class of nanostructured materials for a variety of applications. However, the intrinsic electronic structure of graphene and h-BN atomic sheets limits their direct application in electronic devices. By first-principles density functional theory calculations we demonstrate that band gap of zigzag BN nanoribbons can be significantly tuned under uniaxial tensile strain. The unexpected sensitivity of band gap results from reduced orbital hybridization upon elastic strain. Furthermore, sizable dipole moment and piezoelectric effect are found in these ribbons owing to structural asymmetry and hydrogen passivation. This will offer new opportunities to optimize two-dimensional nanoribbons for applications such as electronic, piezoelectric, photovoltaic, and opto-electronic devices.
Wave functions obtained from plane-wave density-functional theory ͑DFT͒ calculations using normconserving pseudopotential, ultrasoft pseudopotential, or projector augmented-wave method are efficiently and robustly transformed into a set of spatially localized nonorthogonal quasiatomic orbitals ͑QOs͒ with pseudoangular momentum quantum numbers. We demonstrate that these minimal-basis orbitals can exactly reproduce all the electronic structure information below an energy threshold represented in the form of environmentdependent tight-binding Hamiltonian and overlap matrices. Band structure, density of states, and the Fermi surface are calculated from this real-space tight-binding representation for various extended systems ͑Si, SiC, Fe, and Mo͒ and compared with plane-wave DFT results. The Mulliken charge and bond order analyses are performed under QO basis set, which satisfy sum rules. The present work validates the general applicability of Slater and Koster's scheme of linear combinations of atomic orbitals and points to future ab initio tight-binding parametrizations and linear-scaling DFT development.
Nanostructured LiFePO4 (LFP) electrodes have attracted great interest in the Li-ion battery field. Recently there have been debates on the presence and role of metastable phases during lithiation/delithiation, originating from the apparent high rate capability of LFP batteries despite poor electronic/ionic conductivities of bulk LFP and FePO4 (FP) phases. Here we report a potentiostatic in situ transmission electron microscopy (TEM) study of LFP electrode kinetics during delithiation. Using in situ high-resolution TEM, a Li-sublattice disordered solid solution zone (SSZ) is observed to form quickly and reach 10-25 nm × 20-40 nm in size, different from the sharp LFP|FP interface observed under other conditions. This 20 nm scale SSZ is quite stable and persists for hundreds of seconds at room temperature during our experiments. In contrast to the nanoscopically sharp LFP|FP interface, the wider SSZ seen here contains no dislocations, so reduced fatigue and enhanced cycle life can be expected along with enhanced rate capability. Our findings suggest that the disordered SSZ could dominate phase transformation behavior at nonequilibrium condition when high current/voltage is applied; for larger particles, the SSZ could still be important as it provides out-of-equilibrium but atomically wide avenues for Li(+)/e(-) transport.
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