A huge challenge facing scientists is the development of adsorbent materials that exhibit ultrahigh porosity but maintain balance between gravimetric and volumetric surface areas for the onboard storage of hydrogen and methane gas—alternatives to conventional fossil fuels. Here we report the simulation-motivated synthesis of ultraporous metal–organic frameworks (MOFs) based on metal trinuclear clusters, namely, NU-1501-M (M = Al or Fe). Relative to other ultraporous MOFs, NU-1501-Al exhibits concurrently a high gravimetric Brunauer−Emmett−Teller (BET) area of 7310 m2 g−1 and a volumetric BET area of 2060 m2 cm−3 while satisfying the four BET consistency criteria. The high porosity and surface area of this MOF yielded impressive gravimetric and volumetric storage performances for hydrogen and methane: NU-1501-Al surpasses the gravimetric methane storage U.S. Department of Energy target (0.5 g g−1) with an uptake of 0.66 g g−1 [262 cm3 (standard temperature and pressure, STP) cm−3] at 100 bar/270 K and a 5- to 100-bar working capacity of 0.60 g g−1 [238 cm3 (STP) cm−3] at 270 K; it also shows one of the best deliverable hydrogen capacities (14.0 weight %, 46.2 g liter−1) under a combined temperature and pressure swing (77 K/100 bar → 160 K/5 bar).
We report on the measurement of the γp → J/ψp cross section from Eγ = 11.8 GeV down to the threshold at 8.2 GeV using a tagged photon beam with the GlueX experiment. We find the total cross section falls toward the threshold less steeply than expected from two-gluon exchange models. The differential cross section dσ/dt has an exponential slope of 1.67 ± 0.39 GeV −2 at 10.7 GeV average energy. The LHCb pentaquark candidates P + c can be produced in the s-channel of this reaction. We see no evidence for them and set model-dependent upper limits on their branching fractions B(P + c → J/ψp).
We report measurements of the photon beam asymmetry Σ for the reactions γp → pπ 0 and γp → pη from the GLUEX experiment using a 9 GeV linearly-polarized, tagged photon beam incident on a liquid hydrogen target in Jefferson Lab's Hall D. The asymmetries, measured as a function of the proton momentum transfer, possess greater precision than previous π 0 measurements and are the first η measurements in this energy regime. The results are compared with theoretical predictions based on t-channel, quasi-particle exchange and constrain the axial-vector component of the neutral meson production mechanism in these models.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.