In atomic force microscopy, the cantilevers are mounted under a certain tilt angle alpha with respect to the sample surface. In this paper, we show that this increases the effective spring constant by typically 10-20%. The effective spring constant of a rectangular cantilever of length L can be obtained by dividing the measured spring constant by cos2 alpha(1 - 2D tan alpha/L). Here, alpha is the tilt angle and D is the size of the tip. In colloidal probe experiments, D has to be replaced by the radius of the attached particle. To determine the effect of tilt experimentally, the adhesion force between spherical borosilicate particles and planar silicon oxide surfaces was measured at tilt angles between 0 degrees and 35 degrees. The experiments revealed a significant decrease of the mean apparent adhesion force with a tilt of typically 20-30% at alpha = 20 degrees. In addition, they demonstrate that the adhesion depends drastically on the precise position of contact on the particle surface.
Wetting is a universal phenomenon in nature and of interest in fundamental research as well as in engineering sciences. Usually, wetting of solid substrates by liquid drops is described by Young's equation, which relates the contact angle between the liquid and the substrate to the three interfacial tensions. This concept has been widely used and confirmed for macroscopic droplets. On the contrary, it is still matter of debate to what extent this concept is able to explain relations on the micrometer scale and below. The so-called extended Young's equation, which takes account of the specific arrangement of the molecules in the three-phase contact line by implementing a term called "line tension", is frequently used to characterize deviations from the "ideal" Young's case. In this work we tried to look into the dependence of measured contact angles of droplets on their size for a close to ideal system. We measured contact angles of ionic liquid droplets with radii between some tens and some hundreds of nanometers by atomic force microscopy on an ideally flat silicon wafer. We found that the contact angles decreased with decreasing droplet size: smaller droplets showed stronger wetting. This dependence of the contact angle on the droplet radius could not be described with the concept of line tension or the modified Young's equation. We propose simple arguments for a possible alternative concept.
The interaction between solid particles and gas-liquid interfaces is relevant in technological applications. Former studies did focus on detachment-dynamics of particles from thin liquid films or on attachment-dynamics of particles to gas bubbles. Here, we investigated snap-in dynamics of individual micron-sized particles to water drops by means of the colloidal probe technique. The snap-in time (∼0.1 ms) and the snap-in force of hydrophilic and hydrophobic particles were measured. The snap-in time increased with particle size regardless of wettability. The snap-in force increased with particle size and wettability. We show that the snap-in dynamics is dominated by capillarity and inertia.
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