The ability of superhydrophobic surfaces to stay dry, self-clean and avoid biofouling is attractive for applications in biotechnology, medicine and heat transfer 1-10 . It requires that water droplets placed on superhydrophobic surfaces have large apparent contact angles (θ* > 150°) and low roll-off angles (θroll-off < 10°), realized with surfaces having low-surface-energy chemistry as well as micro-or nanoscale surface roughness that minimizes liquid-solid contact 11-17 . But rough surfaces where liquid contacts only a small
The wetting of solid surfaces by fluids has been studied for more than two centuries. However, it was only in recent years that investigations of the first milliseconds of spontaneous drop spreading on solid surfaces started. For non-deformable surfaces, this fast dynamic wetting process is known to be dominated by inertia and controlled by surface wettability. In this work we studied spontaneous spreading of liquids on soft, viscoelastic rubber films with shear moduli |G| between 0.2 and 510 kPa and thickness d between 30 and 160 mm. We found that the early stage of fast wetting of soft surfaces is also dominated by inertia and that the wetting dynamics follows a power law which mainly depends on wettability, but not on softness. This finding allows us to apply fast dynamic wetting measurements for inferring the equilibrium contact angle q eq on soft surfaces. On such surfaces static contact angle measurements with sessile drops would not yield univocal results and Young's equation is not directly applicable. On the other hand, the duration of the fast inertial wetting is controlled by surface softness. This is an indication of a viscoelastic dissipation process occurring during wetting that starts after some characteristic time dependent on the surface tension of the liquid, on the viscosity of the surface, and on the speed of wetting.
In this work, we experimentally investigate the impact of water droplets onto soft viscoelastic surfaces with a wide range of impact velocities. Several impact phenomena, which depend on the dynamic interaction between the droplets and viscoelastic surfaces, have been identified and analyzed. At low We, complete rebound is observed when the impact velocity is between a lower and an upper threshold, beyond which droplets are deposited on the surface after impact. At intermediate We, entrapment of an air bubble inside the impinging droplets is found on soft surfaces, while a bubble entrapment on the surface is observed on rigid surfaces. At high We, partial rebound is only identified on the most rigid surface at We≳92. Rebounding droplets behave similarly to elastic drops rebounding on superhydrophobic surfaces and the impact process is independent of surface viscoelasticity. Further, surface viscoelasticity does not influence drop spreading after impact-as the surfaces behave like rigid surfaces-but it does affect drop recoiling. Also, the postimpact drop oscillation on soft viscoelastic surfaces is influenced by dynamic wettability of these surfaces. Comparing sessile drop oscillation with a damped harmonic oscillator allows us to conclude that surface viscoelasticity affects the damping coefficient and liquid surface tension sets the spring constant of the system.
Moisture-responsive materials are gaining greater interest for their potentially wide applications and the readily access to moisture. In this study, we show the fabrication of moisture-responsive, self-standing films using sustainable cellulose as starting material. Cellulose was modified by stearoyl moieties at first, leading to cellulose stearoyl esters (CSEs) with diverse degrees of substitution (DSs). The films of CSE with a low DS of 0.3 (CSE0.3) exhibited moisture-responsive properties, while CSEs with higher DSs of 1.3 or 3 (CSE1.3 and CSE3) not. The CSE0.3 films could reversibly fold and unfold as rhythmical bending motions within a local moisture gradient due to the ab- and desorption of water molecules at the film surface. By spray-coating CSE3 nanoparticles (NPs) onto CSE0.3 films, moisture-responsive films with non-wetting surface were obtained, which can perform quick reversible bending movements and continuous shape transition on water. Furthermore, bilayer films containing one layer of CSE0.3 at one side and one layer of CSE3 at the other side exhibited combined responsiveness to moisture and temperature. By varying the thickness of CSE0.3 films, the minimal bending extent can be adjusted due to altered mechanical resistances, which allows a bending movement preferentially beginning with the thinner side.
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