Although perovskite solar cells (PSCs) have emerged as a promising alternative to widely used fossil fuels, the involved high‐temperature preparation of metal oxides as a charge transport layer in most state‐of‐the‐art PSCs has been becoming a big stumbling block for future low‐temperature and large‐scale R2R manufacturing process. Such an issue strongly encourages scientists to find new type of materials to replace metal oxides. Except for expensive PC61BM with unmanageable morphology and electrical properties, the past investigation on the development of low‐temperature‐processed and highly efficient electron transport layers (ETLs) has met some mixed success. In order to further enhance the performance of all‐solution‐processed PSCs, we propose a novel n‐type sulfur‐containing small molecule hexaazatrinaphtho[2,3‐c][1,2,5]thiadiazole (HATNT) with high electron mobility up to 1.73 × 10−2 cm2 V−1 s−1 as an ETL in planar heterojunction PSCs. A high power conversion efficiency of 18.1% is achieved, which is fully comparable with the efficiency from the control device fabricated with PC61BM as ETL. This superior performance mainly attributes from more effective suppression of charge recombination at the perovskite/HATNT interface than that between the perovskite and PC61 BM. Moreover, high electron mobility and strong interfacial interaction via SI or SPb bonding should be also positive factors. Significantly, our results undoubtedly enable new guidelines in exploring n‐type organic small molecules for high‐performance PSCs.

BN-embedded polycyclic aromatic hydrocarbons (PAHs) with unique optoelectronic properties are underdeveloped relative to their carbonaceous counterparts due to the lack of suitable and facile synthetic methods. Moreover, the dearth of electron-deficient BN-embedded PAHs further hinders their application in organic electronics. Here we present the first facile synthesis of novel perylene diimide derivatives (B2N2-PDIs) featuring n-type B–N covalent bonds. The structures of these compounds are fully confirmed through the detailed characterizations with NMR, MS, and X-ray crystallography. Further investigation shows that the introduction of BN units significantly modifies the photophysical and electronic properties of these B2N2-PDIs and is further understood with the aid of theoretical calculations. Compared with the parent perylene diimides (PDIs), B2N2-PDIs exhibit deeper highest occupied molecular orbital energy levels, new absorption peaks in the high-energy region, hypsochromic shift of absorption and emission maxima, and decrement of photoluminescent quantum yields. Single-crystal field-effect transistors based on B2N2-PDIs showcase an electron mobility up to 0.35 cm2 V–1 s–1, demonstrating their potential application in optoelectronic materials.

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It is highly desirable to employ n‐type polymers as electron transporting layers (ETLs) in inverted perovskite solar cells (PSCs) due to their good electron mobility, high hydrophobicity, and simplicity of film forming. In this research, the capability of three n‐type donor–acceptor1–donor–acceptor2 (D–A1–D–A2) conjugated polymers (pBTT, pBTTz, and pSNT) is first explored as ETLs because these polymers possess electron mobilities as high as 0.92, 0.46, and 4.87 cm2 (Vs)−1 in n‐channel organic transistors, respectively. The main structural difference among pBTT, pBTTz, and pSNT is the position of sp2‐nitrogen atoms (sp2‐N) in the polymer main chains. Therefore, the effect of different substitution positions on the PSC performances is comprehensively studied. The as‐fabricated p–i–n PSCs with pBTT, pBTTz, and pSNT as ETLs show the maximum photoconversion efficiencies of 12.8%, 14.4%, and 12.0%, respectively. To be highlighted, pBTTz‐based device can maintain 80% of its stability after ten days due to its good hydrophobicity, which is further confirmed by a contact angle technique. More importantly, the pBTTz‐based device shows a neglected hysteresis. This study reveals that the n‐type polymers can be promising candidates as ETLs to approach solution‐processed highly‐efficient inverted PSCs.

Introducing BN units into polycyclic aromatic hydrocarbons expands the chemical space of conjugated materials with novel properties.H owever,i ti sc hallenging to achieve accurate synthesis of BN-PAHs with specific BN positions and orientations.H ere,t hree new parent B 2 N 2perylenes with different BN orientations are synthesized with BN-naphthalene as the building block, providing systematic insight into the effects of BN incorporation with different orientations on the structure,(anti)aromaticity,crystal packing and photophysical properties.T he intermolecular dipole-dipole interaction shortens the p-p stacking distance.The crystal structure,(anti)aromaticity,and photophysical properties vary with the changeo fB No rientation. The revealed BN doping effects may provide ag uideline for the synthesis of BN-PAHs with specific stackings tructures,a nd the synthetic strategy employed here can be extended towardt he synthesis of larger BN-embedded PAHs with adjustable BN patterns.

The unexpected synthesis and characterization of imidazole-fused azaacenes are presented. Their optical and electrochemical properties have been investigated and compared with these of previously reported imidazole-fused azaacenes. Application of these two imidazole-fused azaacenes in memory devices showed distinctly different resistive behaviors.

Using a perturbation method with the aid of MATLAB ® Symbolic Toolbox, a new set of Stokes wave solutions, up to the fifth order, are derived. The new solutions are expressed in terms of free surface profile, velocity potential and wave celerity (or frequency dispersion relation). The solutions in the deep water limit are also deduced and discussed. The new solutions are compared with the existing solutions up to the fifth order. Differences appear among the existing and the present solutions, starting at the third order. The causes for the differences are identified. The characteristic differences were highlighted in the figures for high order solutions of Stokes waves. Numerical examples are provided to quantify the differences between the new fifth-order solutions and Fenton’s, and Skjelbreia and Hendrickson’s solutions.

In article number 1700522, Xiao Wei Sun, Qichun Zhang, and co-workers report the design and synthesis of a new n-type small molecule with a sulfur-containing structure. Employing this small molecule as electron transport layer (ETL), highefficiency planar perovskite solar cells up to 18.1% are realized. This superior performance is mainly due to effective suppression of charge recombination at the perovskite/ETL interface. SOLAR CELLS