The aim of this paper is to analyze the influence of hybrid fiber reinforcement on the properties of a lightweight fly ash-based geopolymer. The matrix includes the ratio of fly ash and microspheres at 1:1. Carbon and steel fibers have been chosen due to their high mechanical properties as reinforcement. Short steel fibers (SFs) and/or carbon fibers (CFs) were used as reinforcement in the following proportions: 2.0% wt. CFs, 1.5% wt. CFs and 0.5% wt. SFs, 1.0% wt. CFs and 1.0% wt. SFs, 0.5% wt. CFs and 1.5% wt. SFs and 2.0% wt. SFs. Hybrid reinforcement of geopolymer composites was used to obtain optimal strength properties, i.e., compressive strength due to steel fiber and bending strength due to carbon fibers. Additionally, reference samples consisting of the geopolymer matrix material itself. After the production of geopolymer composites, their density was examined, and the structure (using scanning electron microscopy) and mechanical properties (i.e., bending and compressive strength) in relation to the type and amount of reinforcement. In addition, to determine the thermal insulation properties of the geopolymer matrix, its thermal conductivity coefficient was determined. The results show that the addition of fiber improved compressive and bending strength. The best compressive strength is obtained for a steel fiber-reinforced composite (2.0% wt.). The best bending strength is obtained for the hybrid reinforced composite: 1.5% wt. CFs and 0.5% wt. SFs. The geopolymer composite is characterized by low thermal conductivity (0.18–0.22 W/m ∙ K) at low density (0.89–0.93 g/cm3).
Space missions will require the capability to build structures on site using local resources. Before 2040, NASA and the European Space Agency want to ensure the possibility of a permanent human residence in shelters on the Moon or Mars. The article analyzed the state of the art in this area based on the literature research. It shows innovative and energy efficient solutions for manufacturing the lunar and Martian shelters based on geopolymer composites. Firstly, the possible materials solutions, with particular attention to the geopolymer composites, are discussed. Next, the previous research is presented, including work based on different kinds of simulants of lunar and Martian regolith. Then, a different approach for manufacturing technologies is presented and the advantages of 3D printing technology are clarified. Eventually, the challenges for further projects are discussed, including energy and cost efficiency problems.
The paper deals with the possibility of using Phase Change Materials (PCM) in concretes and geopolymer composites. The article presents the most important properties of PCM materials, their types, and their characteristics. A review of the latest research results related to their use in geopolymer materials is presented. The benefits of using PCM in building materials include the improvement of thermal comfort inside the building, and also the fact that the additive in the form of PCM reduces thermal gradients and unifies the temperature inside the concrete mix, which can reduce the risk of cracking. The paper also presents a critical analysis related to the feasibility of mass scale implementations of such composites. It was found that the use of PCM in sustainable construction is necessary and inevitable, and will bring a number of benefits, but it still requires large financial resources and time for more comprehensive research. Despite the fact that PCM materials have been known for many years, it is necessary to refine their form to very stable phases that can be used in general construction as well as to develop them in a cost-effective form. The selection of these materials should also be based on the knowledge of the matrix material.
The main aim of this research is to assess different fly ashes as raw materials for the manufacturing of geopolymers. Three different fly ashes have been investigated. First, a conventional fly ash from the Skawina coal power plant (Poland), obtained at a temperature of 900–1100 °C. Second, ultra-fine fly ash from a power plant in China; the side product received at 1300 °C. The third fly ash was waste was obtained after combustion in incineration plants. To predict the properties and suitability of materials in the geopolymerization process, methods based on X-ray analysis were used. The applied precursors were tested for elemental and chemical compounds. The investigations of geopolymer materials based on these three fly ashes are also presented. The materials produced on the basis of applied precursors were subjected to strength evaluation. The following research methods were applied for this study: density, X-ray fluorescence (XRF), X-ray diffraction analysis (XRD), Scanning Electron Microscopy (SEM), flexural and compressive strength. The obtained results show that materials based on fly ashes had a similar compressive strength (about 60 MPa), while significant differences were observed during the bending test from 0.1 to 5.3 MPa. Ultra-fine fly ash had a lower flexural strength compared to conventional fly ash. This study revealed the need for process optimization for materials based on a precursor from a waste incineration plant.
The research described in this article was aimed at determining the influence of hydraulic additives on the foaming process and the stability of the produced geopolymer foams. These foams can be used as insulation materials to replace the currently commonly used insulations such as expanded polystyrene or polyurethane foams. Geopolymers have low thermal conductivity, excellent fire- and heat-resistant properties, and have fairly good mechanical properties. Research on foamed materials shows that they have the highest class of fire resistance; therefore, they are most often used as insulation products in construction. Geopolymer foams were made of aluminosilicate materials (fly ash) and foaming agents (H2O2 and Al powder), and the stabilizers were gypsum and portland cement. Additionally, surfactants were also used. It was found that better foaming effects were obtained for H2O2—it is a better foaming agent for geopolymers than Al powder. When using a hydraulic additive—a stabilizer in the form of cement—lower densities and better insulation parameters were obtained than when using gypsum. Portland cement is a better stabilizer than gypsum (calcium sulfates), although the effect may change due to the addition of surfactants, for example.
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