If the physical properties of C(60) fullerene molecules can be controlled in C(60) products already in use in various applications, the potential for industrial development will be significant. Encapsulation of a metal atom in the C(60) fullerene molecule is a promising way to control its physical properties. However, the isolation of C(60)-based metallofullerenes has been difficult due to their insolubility. Here, we report the complete isolation and determination of the molecular and crystal structure of polar cationic Li@C(60) metallofullerene. The physical and chemical properties of Li@C(60) cation are compared with those of pristine C(60). It is found that the lithium cation is located at off-centre positions in the C(60)-I(h) cage interior and that the [Li(+)@C(60)] salt has a unique two-dimensional structure. The present method of purification and crystallization of C(60)-based metallofullerenes provides a new C(60) fullerene material that contains a metal atom.

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The aerodynamic characteristics of airfoils operating at Re = 4 X JO' were examined, varying the parameters related to the airfoil shape such as thickness, camber, and roughness. Airfoils with good aerodynamic performance at this Re have the following shape characteristics: (I) they are thinner than airfoils for higher Re numbers, (2) they have a sharp leading edge, and (3) they have a camber of about five percent with its maximum camber at about mid-chord. The characteristics of airfoils are .strongly affected by leading edge vortices. The measured two-dimensional airfoil characteristics indicate that the planform, which greatly affects the flight performance of the three-dimensional wing at high Reynolds numbers, has little effect on the flight performance at this Reynolds number. (B) Effect of the Wave Drag. The wave drag is strongly affected by the Froude number, F,. The Froude number, F,. = VoHgc, is 0.19 in this experiment. Wave drags of double-arc sections are shown by Havelock (1923) and Hoerner (1965). Downloaded From: http://fluidsengineering.asmedigitalcollection.asme.org/ on 09/15/2013 Terms of Use: http://asme.org/terms

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A computational fluid dynamic (CFD) modelling approach is used to study the unsteady aerodynamics of the flapping wing of a hovering hawkmoth. We use the geometry of a Manduca sexta-based robotic wing to define the shape of a three-dimensional 'virtual' wing model and 'hover' this wing, mimicking accurately the three-dimensional movements of the wing of a hovering hawkmoth. Our CFD analysis has established an overall understanding of the viscous and unsteady flow around the flapping wing and of the time course of instantaneous force production, which reveals that hovering flight is dominated by the unsteady aerodynamics of both the instantaneous dynamics and also the past history of the wing. <P> A coherent leading-edge vortex with axial flow was detected during translational motions of both the up- and downstrokes. The attached leading-edge vortex causes a negative pressure region and, hence, is responsible for enhancing lift production. The axial flow, which is derived from the spanwise pressure gradient, stabilises the vortex and gives it a characteristic spiral conical shape. <P> The leading-edge vortex created during previous translational motion remains attached during the rotational motions of pronation and supination. This vortex, however, is substantially deformed due to coupling between the translational and rotational motions, develops into a complex structure, and is eventually shed before the subsequent translational motion. <P> Estimation of the forces during one complete flapping cycle shows that lift is produced mainly during the downstroke and the latter half of the upstroke, with little force generated during pronation and supination. The stroke plane angle that satisfies the horizontal force balance of hovering is 23.6 degrees , which shows excellent agreement with observed angles of approximately 20-25 degrees . The time-averaged vertical force is 40 % greater than that needed to support the weight of the hawkmoth.

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