Kinetics of emulsion polymerization of hydrophilic vinyl monomers in the presence of polyvinylpyrrolidone and technological principles of their synthesis are determined. Reasonable technological parameters in the synthesis of copolymers are determined. Physicochemical properties of the synthesized copolymers (surface tension, the size of latex particles, and pH) are determined. Synthesized graft copolymers were used to create high-adhesion polymer-monomer compositions. These compositions have high reactivity at room temperature. It can be regulated by the nature of the polymer matrix and the introduction of comonomers and fillers due to the influence of physicochemical factors on the process of polymer formation. The rate of polymerization and the degree of monomer conversion largely depend on the nature of the polymer matrix. The highest polymerization rate and the maximum degree of conversion are observed when using a copolymer of polyvinylpyrrolidone and polymethylmethacrylate. Materials based on the developed compositions are characterized by a low residual monomer content and high operational properties, such as surface hardness, Vicat softening temperature, and adhesive bond strength to supports of different nature.
Clay-based materials are promising adsorbents for removal of various pollutants from wastewater. This work is aimed to study the changes in structure and adsorption capacity of microwave-treated bentonite after adsorption of lead(II) ions. The structural investigation of the microwave-treated sample reveals that a partial destruction of silica skeleton takes place, and new surface nucleation centers are formed during microwave processing. The adsorption of Pb 2+ on natural bentonite occurs on heterogeneous adsorption sites, whereas the removal of lead on microwave-treated sample is accompanied by the formation of plumbophyllite microcrystals. The natural and microwave-treated adsorbents were tested for lead adsorption in batch experiments. The results were fitted according to Langmuir, Freundlich, Toth, Redlich-Peterson, and Langmuir-Freundlich isotherms of adsorption. The microwave-treated samples revealed substantially higher efficiency towards the removal of lead, their maximal adsorption capacity was 114.7 mg g-1 , whereas natural samples showed only 31 mg g-1 .
Novoyavorivsk is located near large sulfur deposits in a transborder with Poland. The existing sanitation system in Novoyavorivsk is imperfect. Municipal wastes are stored in cloughs, ravines, river valleys. This causes an environmental hazard, as polluted wastewater is discharged to the water bodies. The aim of the work is environmental hazard assessment of Novoyavorivsk landfill. The tasks of the research are as follows: determination of chlorides and sulfates content in the landfill edaphotopes; measurement of power of equivalent dose of photon radiation. Determination of chlorides and sulfates was carried out by quantitative and qualitative methods. The equivalent dose of photon radiation was measured by dosimeter by SOEKS USA, LLC. In different sites of the landfill chlorides and sulfates content differs. The most polluted areas are at the distance of 10 m and 50 m from the foot. At a distance of 100 m from the landfill, the concentration of chlorides reduces to 0.001% (5 cm) and 0.1% (10 cm and 20 cm). High sulfate content is observed at 10 m from the foot of the landfill (1% in the 10 cm and 20 cm horizons). The power of the equivalent dose at a height of 10 m from the south side exceeds the pollution standard of 0.3 μSv/h and equals 0.32 μSv/h.
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