This paper presents temperature-dependent properties and fire resistance of geopolymer foams made of ground basalt fibers, aluminum foaming agents, and potassium-activated metakaolin-based geopolymers. Temperature-dependent properties of basalt-reinforced geopolymer foams (BGFs) were investigated by a series of measurements, including apparent density, water absorption, mass loss, drying shrinkage, compressive and flexural strengths, XRD, and SEM. Results showed that the apparent density and drying shrinkage of the BGFs increase with increasing the treated temperature from 400 to 1200 °C. Below 600 °C the mass loss is enhanced while the water absorption is reduced and they both vary slightly between 600 and 1000 °C. Above 1000 °C the mass loss is decreased rapidly, whereas the water absorption is increased. The compressive and flexural strengths of the BGFs with high fiber content are improved significantly at temperatures over 600 °C and achieved the maximum at 1200 °C. The BGF with high fiber loading at 1200 °C exhibited a substantial increase in compressive strength by 108% and flexural strength by 116% compared to that at room temperature. The enhancement in the BGF strengths at high temperatures is attributed to the development of crystalline phases and structural densification. Therefore, the BGFs with high fiber loading have extraordinary mechanical stability at high temperatures. The fire resistance of wood and steel plates has been considerably improved after coating a BGF layer on their surface. The coated BGF remained its structural integrity without any considerable macroscopic damage after fire resistance test. The longest fire-resistant times for the wood and steel plates were 99 and 134 min, respectively. In general, the BGFs with excellent fire resistance have great potential for fire protection applications.
The paper presents the results of research concerning the influence of micromaterials on the heat conductivity coefficient λ, specifically heat Cp and thermal diffusivity a of modified gypsum and geopolymer. Microspheres, hydroxyethyl methylcellulose (HEMC) polymer, and aerogel were used as the gypsum’s modifying materials. The study also investigated an alkali potassium-activated methakaolin-based geopolymer with the addition of aluminium dust. During the measurements of thermal parameters, the nonstationary method was chosen, and an Isomet device—which recorded the required physical quantities—was used. When compared to the reference sample, a decrease in the thermal conductivity and diffusivity of the hardened gypsum— and a simultaneous increase in specific heat—was observed with the addition of micromaterials. The geopolymer sample was characterized by the lowest value of thermal conductivity, equal to 0.1141 W/(m·K). It was over 62% lower than the reference sample containing only gypsum. The experimental values of the thermal conductivity of the gypsum samples with the addition of HEMC, aerogel and microspheres were, respectively, over 23%, 6%, and 8% lower than those of the unmodified gypsum samples. The lowest values of thermal conductivity were observed in the case of the gypsum samples modified with polymer; this resulted from the fact that the polymer caused the greatest change in the structure of the gypsum’s composite, which were expressed by the lowest density and highest porosity.
The paper presents an assessment of the impact of using additives on the strength of a binding material, i.e., building gypsum, and also the phase transformation that takes place in it. Microspheres, aerogel and polymer (HEMC) additives were added to a building gypsum slurry with a water to gypsum ratio of 0.75. In order to investigate their influence on bending strength, compressive strength, and the effect of high temperatures, differential scanning calorimetry (DSC), as well as tests of the multicomponent binder, were carried out in accordance with the applicable PN-EN 13279-2:2005 standard. The obtained test results allowed to determine that the used additives influenced the strength parameters of the obtained composites. It was shown that the applied additives decreased the compressive and bending strength of the modified gypsum. Despite these properties, the obtained gypsum materials are environmentally friendly because they reuse wastes, such as microspheres. Out of all the applied additives, the use of microspheres in an amount of 10% caused a decrease in the bending strength by only 10%, and an increase in the compressive strength by 4%.
This paper reports the results of an experimental investigation on the mechanical properties of geopolymer foams incorporating filler from the coke dust waste (CDW). In this work, CDW was used to replace a part of geopolymer paste at 5%, 10%, 20%, and 30% by geopolymer binder mass. The physico-mechanical properties and thermal resistance against high temperatures of CDW/geopolymer foams are presented. The primary results obtained show that the use of CDW in the production of geopolymer foam composites made it possible for them to achieve relatively good mechanical properties. However, the incorporation of the CDW into the geopolymer had a slightly negative effect on thermal conductivity, but significantly improved the mechanical strength of the final product. Moreover, this waste also helped the composite foam to achieve a structure with more uniform open pores distribution, compared to the pure foam. After exposure to elevated temperatures, the residual strength of the composite foams maintained well compared to the pure foams.
The paper presents the results of research concerning the influence of a metallic micromaterial on the thermal conductivity λ, specific heat Cp, and thermal diffusivity a of modified geopolymers. Iron oxide in the form of powder with an average granulation of 10 μm was used as the geopolymer-modifying material. The research concerned geopolymer composite samples with metakaolin (activated with potassium silicate) and the addition of iron in amounts ranging from 0.5% to 2.5% in relation to the weight of the metakaolin. Additionally, the samples were modified with sand and fireclay in two different amounts—1:1 and 1:1.2 in relation to the metakaolin. The addition of fireclay caused a decrease in the thermal conductivity of the composites by 30% when compared to the samples with the addition of sand. The lowest value of the thermal conductivity coefficient λ was obtained for the geopolymer with metakaolin and fireclay. When the ratio of these components in the composite was 1:1, the value of thermal conductivity was equal to 0.6413 W/(m·K), while in the case of their ratio being 1:1.2, it was equal to 0.6456 W/(m·K). In the samples containing fireclay, no significant influence of the added iron on the values of thermal conductivity was noticed. In the case of the geopolymer with sand, the effect was noticeable, and it was most visible in the samples containing metakaolin and sand in the ratio of 1:1.2. It was noticed that with an increase in the addition of Fe, the thermal conductivity of the composite increased.
The article presents preliminary results in studying reinforced and light-weight geopolymers, which can be employed in buildings, especially for walling. Such materials are very promising for the construction industry having great potential due to their favorable properties such as high mechanical strengths, low thermal conductivity, and low density. Moreover, they also exhibit several advantages from an economic and ecological point of view. The present study exanimated the use of specific fillers for the metakaolin-based light-weight geopolymers, emphasizing the above-mentioned physical properties. This research also investigated the electromagnetic shielding ability of the carbon grid built into the light-weight geopolymer structure. According to the study, the most suitable materials to be used as fillers are polystyrenes, along with hollow ceramic microsphere and Liapor. The polystyrene geopolymer (GPP) achieves five times lower thermal conductivity compared to cement concretes, which means five times lower heat loss by conduction. Furthermore, GPP is 28% lighter than the standard geopolymer composite. Although the achieved flexural strength of GPP is high enough, the compressive strength of GPP is only 12 MPa. This can be seen as a compromise of using polystyrene as a filler. At the same time, the results indicate that Liapor and hollow ceramic microsphere are also suitable fillers. They led to better mechanical strengths of geopolymer composites but also heavier and higher thermal conductivity compared to GPP. The results further show that the carbon grid not only enhances the mechanical performances of the geopolymer composites but also reduces the electromagnetic field. Carbon grids with grid sizes of 10 mm × 15 mm and 21 mm × 21 mm can reduce around 60% of the Wi-Fi emissions when 2 m away from the signal transmitter. Moreover, the Wi-Fi emission was blocked when the signal transmitter was at a distance of 6 m.
This paper presents an experimental research on the mechanical properties of the hybrid composite thin-plates of the short basalt fibers (CBFs)/carbon textile-reinforced geomortar. The effect of fiber contents and lengths of CBFs on the flexural behavior of carbon textile-reinforced geopolymer specimens (TRGs) was investigated by the four-point flexural strength and Charpy impact test. The experimental results of hybrid TRGs, on the one hand, were compared with reference TRGs, without CBF addition; on the other hand, they were compared with the results of our previous publication. According to the mixing manner applied, fresh geomortar indicated a marked reduction in workability, increasing the CBF loading. Furthermore, using CBFs with lengths of 12 mm and 24 mm makes it easy to form the fiber clusters in geomortar during mixing. According to all the CBF loadings used, it was found that TRGs showed a significant improvement in both static and dynamic flexural strength. However, the failure mode of these TRGs is similar to that of the reference TRGs, described by the process of fiber debonding or simultaneously fiber debonding and collapse. In comparison with our prior work results, neither the CBF dose levels nor the fiber lengths used in this work have yielded a positive effect on the failure manner of TRGs. According to the results of the Charpy impact test, this reveals that the anchoring capacity of textile layers in geomortar plays an important role in specimens’ strength.
The article deals with the investigation of geopolymer foams (GFs) synthesized using by-products coming from the (i) screening-, (iv) pyrolysis-, (iii) dust abatement- and (iv) fusion-processes of the secondary aluminum industry. Based on principles of the circular economy to produce new technological materials, the experimental study involves industrial by-products management through the recovery, chemical neutralization, and incorporation of these relatively hazardous waste into the GFs. The geopolymeric matrix, consisting of metakaolin (MK) and silica sand (SA) with a 1:1 wt.% ratio, and chopped carbon fibers (CFs, 1 wt.% MK), was doped with the addition of different aluminum-rich industrial by-products with a percentage from 1 to 10 wt.% MK. The gas (mainly hydrogen) produced during the chemical neutralization of the by-products represents the foaming agents trapped in the geopolymeric structure. Several experimental tests were carried out to characterize the mechanical (flexural, compressive, and Charpy impact strengths) and thermal properties (thermal conductivity, and diffusivity, and specific heat) of the GFs. Results identify GFs with good mechanical and thermal insulation properties, encouraging future researchers to find the best combination (for types and proportions) of the different by-products of the secondary aluminum industry to produce lightweight geopolymer foams. The reuse of these industrial by-products, which according to European Regulations cannot be disposed of in the landfill, also brings together environmental sustainability and safe management of hazardous material in workplaces addressed to the development of new materials.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.