An important milestone in the development of photovoltaic thin-film solar cells is the achievement of 15% conversion efficiency. This letter describes the highest efficiency single junction thin-film cell reported to date. An active area efficiency of 14.8% is obtained with the cell structure n-ZnO/n-CdS/p-CuInSe2 deposited on a soda-lime glass substrate. The current achievements are due to improved properties of the CuInSe2 layer and the heterojunctions compared to previously reported results. The rate and substrate temperature profiles used during the coevaporation process yield a relatively large-grained material with very strong 〈112〉 orientation and low porosity. This results in reduced recombination rates, hence higher open circuit voltage and fill factor.
SrS:Ce is an intensively investigated phosphor due to its blue-green electroluminescence, which shows efficient blue emission after filtering. Recently reported devices based on this material have demonstrated a luminous efficiency of 1.6 lm/W. The luminescence properties of SrS:Ce,X (X=Na or Cl) have been studied on powders and thin films. It is shown that a high density of traps in SrS:Ce,X occurs. The interaction of Ce3+ with traps gives rise to a phosphorescence. An energy transfer from Ce3+ to traps is responsible for an observed luminescence quenching in the presence of high electric fields. Moreover, the traps are electrically active and are involved in the electroluminescence process. The observed energy transfer is proposed to be the dominant excitation mechanism of Ce3+ in electroluminescence. It is demonstrated for thin films that the defect density increases with doping; therefore, the luminescence yield is already limited at doping concentrations below the onset of the concentration quenching. Thus, the prepared SrS:Ce,Cl thin films show a lower photoluminescence yield than powders. It is concluded that an undisturbed Ce incorporation into SrS thin films has not been achieved so far, although high electroluminescence efficiencies (1.6 lm/W) have been obtained.
We present our hybrid InP to SiN TriPleX integration interface with a novel alignment technique and its application to complex photonic integrated circuits. The integration interface comprises vertical alignment stops, which simplify the alignment process and allow for array integration with the same simplicity as for single dies. Horizontal alignment is carried out by utilizing optical backscatter reflectometry to get an active feedback signal without the need to operate the chip. Thus, typical contacting limitations of active flip-chip alignment are overcome. By using this method, we demonstrate the integration of InP DFB lasers with more than 60 mW of optical power coupled to a SiN waveguide with an averaged coupling loss of -2.1 dB. The hybrid integration process is demonstrated for single dies as well as full arrays. We evaluate the feasibility of the assembly process for complex photonic integrated circuits by integrating an InP gain chip to a SiN TriPleX external cavity. The process proves to be well suited and allows monitoring chip quality during assembly. A fully functional hybrid integrated tunable laser is fabricated, which is capable of full C-band tuning with optical output power of up to 60 mW.
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