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The current understanding and developments of phase separation technology based on ultrasonic standing waves (USWs) are reviewed. Most previous reviews have focused on microscale applications of this technology in the fields of biological materials and food processing. This review covers different applications of ultrasonic separation technology, especially in petrochemical industry. The kinetic mechanism of ultrasonic, design of reactors, separation principles, and related applications are discussed in detail. We lay special stress on the motion characteristics of particles in USWs. According to the particle numbers, particle properties, and frequency characteristics, the separation principles are reasonably categorized as: (1) Bands effect; (2) Acoustophoretic coefficient; (3) Particle density; (4) Sweep frequency. Diverse separation principles improve the universality of ultrasonic separation technology. However, acoustic streaming and acoustic cavitation are two of the main challenges in the application of ultrasonic separation. Based on the current research, the future research can focus on the following aspects: (1) Explore the mechanism of ultrasonic demulsification; (2) Establish unified evaluation criteria for acoustic separation systems; (3) Develop the basis for determination of acoustic cavitation and non-cavitation.

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