In situ ion-beam-induced luminescence measurements reveal a strong enhancement of the Cr3+ emission yield in electrically conductive chromium doped β-Ga2O3 single crystals upon proton irradiation. The observed effect can be explained based on the Fermi-level pinning caused by radiation defects. This pinning of the Fermi level activates deep carrier traps that can act as sensitizers of the Cr3+ emission. In agreement with this model, in semi-insulating samples, where the Fermi level lies deep in the bandgap, the Cr3+ emission is present already in as-grown samples, and no enhancement of its intensity is observed upon proton irradiation. The boost of the Cr3+ emission yield by irradiation, observed in conductive samples, is reversed by thermal annealing in argon at temperatures above 550 °C for 30 s. The results reveal a high potential of Cr-doped β-Ga2O3 for in situ and ex situ optical radiation detection and dosimetry.

A scalable laser scribing approach to produce ZnO decorated laser-induced graphene in a unique laser-processing step was developed. The produced composites reveal promising optical and electrochemical properties to be applied in sensing devices.

Zinc oxide (ZnO)/laser-induced graphene (LIG) composites were prepared by mixing ZnO, grown by laser-assisted flow deposition, with LIG produced by laser irradiation of a polyimide, both in ambient conditions. Different ZnO:LIG ratios were used to infer the effect of this combination on the overall composite behavior. The optical properties, assessed by photoluminescence (PL), showed an intensity increase of the excitonic-related recombination with increasing LIG amounts, along with a reduction in the visible emission band. Charge-transfer processes between the two materials are proposed to justify these variations. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy evidenced increased electron transfer kinetics and an electrochemically active area with the amount of LIG incorporated in the composites. As the composites were designed to be used as transducer platforms in biosensing devices, their ability to detect and quantify hydrogen peroxide (H2O2) was assessed by both PL and CV analysis. The results demonstrated that both methods can be employed for sensing, displaying slightly distinct operation ranges that allow extending the detection range by combining both transduction approaches. Moreover, limits of detection as low as 0.11 mM were calculated in a tested concentration range from 0.8 to 32.7 mM, in line with the values required for their potential application in biosensors.

Antibiotic pollution of freshwaters and even food products has become an important concern worldwide. Hence, it is of utmost importance to develop cost-effective and reliable devices that can provide information on the presence of such contaminants to the general population. In the present work, zinc oxide (ZnO) nanotetrapods (NTP) produced via a high yield laser processing approach were used as transducers in a luminescent-based immunosensor to detect tetracycline (TC). These tetrapodal structures present needleshaped branches with a high aspect ratio, exhibiting lengths from hundreds of nanometers to a few micrometers and an average thickness of tens of nanometers, providing a high surface area for bioreceptor immobilization and analyte reaction, which is quite desirable in a transducer material. Besides, these ZnO NTP display intense photoluminescence (PL) at room temperature, making such a signal rather promising for transduction. Indeed, the intensity of the ZnO PL signal was seen to correlate with the TC concentration. The PL quenching with increasing analyte concentration is explained considering the rise in the bending of the electronic bands of the semiconductor near its surface due to increased charge density at this region, induced by the interaction between the bioreceptor (anti-TC antibodies) and the TC molecules. As a larger depletion width (and potential barrier) is promoted near the surface, the excitonic recombination probability is reduced and, consequently, the PL intensity in the ultraviolet spectral region, allowing us to use this relationship as a sensing mechanism. This information enabled us to define a calibration curve for TC quantification in the 0.001 to 1 μg L −1 range, which is the range of interest of this antibiotic in freshwaters. A limit of detection (LOD) of ∼1.2 ng L −1 is reported, corresponding to one of the lowest LOD found in the literature for this antibiotic, indicating that the present ZnO NTPbased biosensors rival the current state-of-the-art ones.

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Zinc oxide (ZnO) is a wide bandgap semiconductor material that has been widely explored for countless applications, including in biosensing. Among its interesting properties, its remarkable photoluminescence (PL), which typically exhibits an intense signal at room temperature (RT), arises as an extremely appealing alternative transduction approach due to the high sensitivity of its surface properties, providing high sensitivity and selectivity to the sensors relying on luminescence output. Therefore, even though not widely explored, in recent years some studies have been devoted to the use of the PL features of ZnO as an optical transducer for detection and quantification of specific analytes. Hence, in the present paper, we revised the works that have been published in the last few years concerning the use of ZnO nanostructures as the transducer element in different types of PL-based biosensors, namely enzymatic and immunosensors, towards the detection of analytes relevant for health and environment, like antibiotics, glucose, bacteria, virus or even tumor biomarkers. A comprehensive discussion on the possible physical mechanisms that rule the optical sensing response is also provided, as well as a warning regarding the effect that the buffer solution may play on the sensing experiments, as it was seen that the use of phosphate-containing solutions significantly affects the stability of the ZnO nanostructures, which may conduct to misleading interpretations of the sensing results and unreliable conclusions.

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Zn1+xGa2-2xGexO4 (ZGGO:Cr)-persistent phosphor, with a molar fraction, x, of x = 0.1, doped with a 0.5% molar of chromium, was synthesised via solid-state reaction at 1350 °C for 36 h. X-ray diffraction measurements and Raman spectroscopy evidence a single crystalline phase corresponding to the cubic spinel structure. Room temperature (RT) photoluminescence (PL) and afterglow decay profiles were investigated using above and below bandgap excitation. In both cases, persistent PL was observed for almost 8 h, mainly originating from a Cr3+ defect, the so-called N2 optical centre. RT PL excitation and diffuse reflectance allow identification of the best pathways of Cr3+ red/NIR emission, as well as estimation of the ZGGO bandgap energy at 4.82 eV. An in-depth investigation of the observed luminescence at 15 K and temperature‑dependent PL under site‑selective excitation reveals the spectral complexity of the presence of several optically active Cr3+ centres in the ZGGO host that emit in almost the same spectral region. Furthermore, the temperature dependence of the R‑lines’ intensity indicates the existence of thermal populating processes between the different optical centres. Such observations well account for a wide distribution of defect trap levels available for carrier capture/release, as measured by the persistent luminescence decay, from which the carriers are released preferentially to the N2 Cr3+-related optical centre.