A green, template-free and easy-to-implement strategy was developed to access holey g-C N (GCN) nanosheets doped with carbon. The protocol involves heating dicyandiamide with β-cyclodextrin (βCD) prior to polymerization. The local symmetry of the GCN skeleton is broken, yielding CxGCN (x corresponds to the initial amount of βCD used) with pores and a distorted structure. The electronic, emission, optical and textural properties of the best-performing material, C2GCN, were significantly modified as compared to bulk GCN. The spectroscopic and luminescent features of C2GCN show the characteristic π-π* electronic transition of GCN, accompanied by much stronger n-π* electronic transitions owing to the porous and distorted network. These new electronic transitions, along with the presence of additional carbon synergistically contributed to enhanced visible light absorption and restrained recombination of electron-hole pairs. Steady-state and time-resolved photoluminescence showed an effective quench of the fluorescence emission, accompanied by a decrease of fluorescence lifetime of C2GCN (2.20 ns) in comparison with GCN (5.85 ns), owing to the delocalization of electron and holes to new recombination centers. The photocatalytic activity of C2GCN was attributed to efficient charge carrier separation and improved visible-light absorbing ability. As result, C2GCN exhibited ∼5 times higher photocatalytic H generation under visible light than bulk GCN.

In situ ion-beam-induced luminescence measurements reveal a strong enhancement of the Cr3+ emission yield in electrically conductive chromium doped β-Ga2O3 single crystals upon proton irradiation. The observed effect can be explained based on the Fermi-level pinning caused by radiation defects. This pinning of the Fermi level activates deep carrier traps that can act as sensitizers of the Cr3+ emission. In agreement with this model, in semi-insulating samples, where the Fermi level lies deep in the bandgap, the Cr3+ emission is present already in as-grown samples, and no enhancement of its intensity is observed upon proton irradiation. The boost of the Cr3+ emission yield by irradiation, observed in conductive samples, is reversed by thermal annealing in argon at temperatures above 550 °C for 30 s. The results reveal a high potential of Cr-doped β-Ga2O3 for in situ and ex situ optical radiation detection and dosimetry.

International audienceMagnetoresistive and magnetoresonance measurements carried out on patterned perpendicular magnetic tunnel junction pillars and full-sheet films reveal magnetic inhomogeneities of FeCoB free layer grown on MgO and coated with Ta. At low FeCoB thicknesses, the layer behaves as an ensemble of weakly coupled grains resulting in a decrease of the free-layer thermal stability. In contrast, for thicker layers, the grains become more strongly coupled but strong magnetic inhomogeneities remain, yielding the emergence and further increase of a second-order magnetic anisotropy term (∼K 2eff cos 4 θ), eventually resulting in an easy-cone anisotropy. We show that the static and dynamic magnetic properties of such a free layer can be successfully described by a granular model with three thickness-dependent parameters: mean perpendicular anisotropy of the grains, grain-to-grain anisotropy distribution, and intergrain exchangelike coupling strength. Easy-cone anisotropy may help reduce the stochasticity of the spin transfer torque switching. However, it arises at intermediate values of the intergrain exchange coupling where the spin transfer torque (STT) switching efficiency is degraded, as shown by multimacrospin modeling. This is due to the excitation of exchange modes contributing weakly to the STT switching process while dissipating part of the STT energy

We have used the ferromagnetic resonance in the X-band (9.37 GHz) to investigate the effect of 400 keV Ar + irradiation on the perpendicular magnetic anisotropy (PMA) and Gilbert damping parameter, α, of double-MgO free layers designed for application in perpendicular magnetic tunnel junctions. The samples comprised a MgO / Fe72Co8B20 / X(0.2 nm) / Fe72Co8B20 / MgO layer stack, where X stands for an ultrathin Ta or W spacer. Samples with two different total FeCoB layer thicknesses, tFCB = 3.0 nm and tFCB = 2.6 nm, were irradiated with ion fluences ranging from 10 12 cm-2 to 10 16 cm-2. The effective first-order PMA field, BK1, decreased nearly linearly with the logarithm of the fluence for both FeCoB thicknesses and spacer elements. The decrease in BK1, which is likely caused by an ion-induced intermixing at the FeCoB/MgO interfaces, resulted in a reorientation of the magnetization of the free layers with tFCB = 2.6 nm, initially exhibiting a perpendicular easy-axis anisotropy. For intermediate fluences, 10 13 cm-2 and 10 14 cm-2 , easy-cone states with different cone angles could be induced in the free layer with a W spacer. Importantly, no corresponding increase in the Gilbert damping was observed. This study shows that ion irradiation can be used to tune the easy-cone anisotropy in perpendicular magnetic tunnel junctions, which is interesting for spintronic applications such as spin-torque magnetic memories, oscillators and sensors.

In this study, we investigated the temperature behavior of phase-shifted long-period fiber gratings (PS-LPFGs) inscribed in two types of optical fiber: B/Ge and SMF28. The experiments were carried out from 5 to 305 K using a superconducting quantum interference device magnetometer. The average temperature sensitivity obtained of −0.43 nm/K for PS-LPFGs inscribed in the B/Ge fiber is one order of magnitude larger than for PS-LPFGs inscribed in the SMF28 fiber, in the 60-240 K range. Values ranging from −0.08 nm/K up to 0.2 nm/K were obtained in the 5-35 K temperature range, which are considerably better than previous results achieved for metal-coated FBGs and also for LPFGs inscribed in a similar B/Ge codoped fiber. Nevertheless, further work is required in order to correctly address sensor reliability. Index Terms-Cryogenic temperatures, long-period fiber grating, optical fiber sensor. I. INTRODUCTION S YSTEMS operating at cryogenic temperatures are becoming increasingly important in the energy sector, transportation, and medicine technology. Cryogenic fuels such as liquid hydrogen (also employed in aerospace vehicles), oxygen and liquefied natural gas are often considered as major energy alternatives to fossil fuels. To ensure the safe storage, transfer and dispensing of liquefied fuels, highly sensitive and reliable Manuscript

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