The objective of
the work was to improve the leaching resistance
of fire-retardant (FR) modified wood by the incorporation of a thermoset
resin. Here, Scots pine (
Pinus sylvestris
L.) sapwood was impregnated with melamine formaldehyde (MF) resin
and hydrophilic FRs guanyl-urea phosphate/boric acid by a vacuum-pressure
treatment. Resistance to leaching of FR-modified wood was evaluated,
after conducting an accelerated aging test according to European standard
EN 84. Inductively coupled plasma analysis showed that the incorporation
of MF resin significantly reduced the leachability of FRs. Scanning
electron microscopy/energy-dispersive X-ray spectrometry revealed
that the mechanism of water resistance was by doping the FRs into
MF resin microspheres. Fourier transform infrared spectra showed the
chemical functionality changes of FR-modified wood such as the formation
of methylene bridges by drying the modified wood specimens. An increase
in the thermal stability of FR-modified wood was confirmed by thermal
gravimetric analysis. Excellent fire performance of FR-modified wood
after leaching was affirmed by the limiting oxygen index and cone
calorimeter tests.
Formaldehyde is a toxic chemical commonly found in the environment. Owing to its increased usage, its incidence has also increased, and there is a need to determine the concentration of formaldehyde for the pollution control purposes. In general, spectrophotometric methods are easy to perform, low-cost, selective and sensitive, but every spectrophotometric method has its advantages and disadvantages, which are an important factor when selecting the method for determination of formaldehyde. Therefore, the aim of the research described in this paper was to compare the current spectrophotometric methods and to summarize their advantages and disadvantages.
Optically transparent wood is a type of composite material, combining wood as a renewable resource with the optical and mechanical properties of synthetic polymers. During this study, the effect of monochromatic UV-C (λ—250 nm) radiation on transparent wood was evaluated. Samples of basswood were treated using a lignin modification method, to preserve most of the lignin, and subsequently impregnated with refractive-index-matched types of acrylic polymers (methyl methacrylate, 2-hydroxyethyl methacrylate). Optical (transmittance, colour) and mechanical (shore D hardness) properties were measured to describe the degradation process over 35 days. The transmittance of the samples was significantly decreased during the first seven days (12% EMA, 15% MMA). The average lightness of both materials decreased by 10% (EMA) and 17% (MMA), and the colour shifted towards a red and yellow area of CIE L*a*b* space coordinates. The influence of UV-C radiation on the hardness of the samples was statistically insignificant (W+MMA 84.98 ± 2.05; W+EMA 84.89 ± 2.46), therefore the hardness mainly depends on the hardness of used acrylic polymer. The obtained results can be used to assess the effect of disinfection of transparent wood surfaces with UV-C radiation (e.g., due to inactivation of SARS-CoV-2 virus) on the change of its aesthetic and mechanical properties.
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