Four sustainable materials including a recycled polypropylene blend, polybutylene adipate terephthalate, and two grades of polylactic acid are compared to a reference isotactic polypropylene. Tensile specimens were produced using a two-cavity, hot runner mold with fully automatic cycles per standard industrial practices to investigate the effect of melt temperature, injection velocity, cycle time, and screw speed on the mechanical properties. Multiple regression and principal component analyses were performed for each of the materials. Results indicated that all the materials were readily processed using a hot runner, and the mechanical properties exhibited minimal variation. To the extent that losses in mechanical properties were observed, the results indicated that the losses were correlated with thermal degradation as independently characterized by thermal gravimetric analysis. Such losses can be minimized by reducing melt temperature and cycle time, leading to a reduction of the environmental impact of injection molding processes.
Economic and environmental costs are assessed for four different plastics manufacturing processes, including cold and hot runner molding as well as stock and upgraded material extrusion three dimensional (3D) printers. A larger stock 3D printer was found to provide a melting capacity of 14.4 ml/h, while a smaller printer with an upgraded extruder had a melting capacity of 36 ml/h. 3D printing at these maximum melting capacities resulted in specific energy consumption (SEC) of 16.5 and 5.28 kWh/kg, respectively, with the latter value being less than 50% of the lowest values reported in the literature. Even so, analysis of these respective processes found them to be only 2.9% and 3.8% efficient relative to their theoretical minimum energy requirements. By comparison, cold and hot runner molding with an all‐electric machine had SEC of 1.28 and 0.929 kWh/kg, respectively, with efficiencies of 9.9% and 13.6% relative to the theoretical minima. Breakeven analysis considering the cost and carbon footprint of mold tooling found injection molding was preferable at a production quantity of around 70,000 units. Parametric analysis of model inputs indicates that the breakeven quantities are robust with respect to carbon tax incentives but highly dependent on mold costs, labor costs, and part size. Dimensional and mechanical properties of the molded and 3D printed specimens are also characterized and discussed.
The generation of submicron structures on plastic part surfaces can be used to modify their wetting properties allowing the creation of superhydrophobic surfaces. The modified wetting behavior can allow functionalities such as fluid collection or transport, which are critical for microfluidics. Consistent manufacturing is achieved through surface replication and process characterization. In this work, submicron structures were generated on steel mold inserts using ultrafast femtosecond laser and then replicated by micro injection molding on polypropylene and polylactic acid. Samples with Laser-Induced Periodic Surface Structures (LIPSS) were fabricated using a femtosecond laser and characterized to investigate the effects of mold temperature, texture orientation, and material selection on the dynamic contact angle. The dynamic wetting functionality of the surfaces was investigated by analysis of the advancing and receding contact angles. The hysteresis obtained from the dynamic measurements provides information about the fluid/texture interaction dynamics. The experimental results show that the effects of mold temperature and drop orientation are only significant for the advancing contact angles. The large contact angle hysteresis suggests a parahydrophobic wetting behavior for the manufactured plastic parts.
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