Within the silicon photovoltaics (PV) community, there are many approaches, tools, and input parameters for simulating solar cells, making it difficult for newcomers to establish a complete and representative starting point and imposing high requirements on experts to tediously state all assumptions and inputs for replication. In this review, we address these problems by providing complete and representative input parameter sets to simulate six major types of crystalline silicon solar cells. Where possible, the inputs are justified and up-to-date for the respective cell types, and they produce representative measurable cell characteristics. Details of the modeling approaches that can replicate the simulations are presented as well. The input parameters listed here provide a sensible and consistent reference point for researchers on which to base their refinements and extensions.
Current studies reveal the expectation that photovoltaic (PV) energy conversion will become the front-runner technology to stem against the extent of global warming by the middle of this century. In 2019, the passivated emitter and rear cell (PERC) design has taken over the majority of global photovoltaic solar cell production. The objective of this paper is to review the fundamental physics of the underlying cell architecture, its development over the past few decades to an industry main stream product, as well as an in-depth characterization of current cells and the future potential of the device structure. The early development of PERCs was set by an intriguing series of improvements starting in 1989 and resulting in a long-standing energy conversion efficiency record of 25.0% set up in 1999. It took a decade of intense technological development to implement this structure as an upgrade to existing production lines and another decade to increase the efficiency of industrially manufactured cells to over 22%. Our analysis of state-of-the-art large-area screen-printed PERCs is based on the pilot-line technology in the Photovoltaic Technology Evaluation Center at the Fraunhofer ISE, which is assumed to be representative of current state-of-the art cell processing. The main recent cell efficiency improvements have been achieved thanks to fine line metallization taking advantage of the high quality emitter formation and passivation and to improvements in material quality. In order to enhance the energy yield of the PV modules, innovations in interconnection technology like multibusbar and shingling technology as well as bifaciality are supported by PERC developments. Over the years, ongoing improvements have been made in the understanding of PERCs by analytical and numerical modeling of these devices. We show a study based on 3D numerical modeling and an extrapolation of the PERC device structure and technology to achieve an efficiency of 26%. This result surpasses earlier investigations due to the combination of technology components, as further improved front contact and emitter design as well as rear passivation and mirrors. We expect that PERCs can also play a strong role at the bottom of multijunction solar cells and will defend a strong position in global PV production beyond the end of the now starting decade.
After completion of the solar cell manufacturing process the current-density versus voltage curves (J(U) curves) are measured to determine the solar cell's efficiency and the mechanisms limiting the efficiency. An accurate and robust analysis of the measured curves is essential. In this work it is shown that fitting the two-diode model is inappropriate to quantify recombination in the space charge region and ohmic losses due to series resistance. Three fill factors, namely the fill factor of the illuminated J(U) curve, the pseudo fill factor of the sunsVoc curve and the ideal fill factor of the single diode model, are the base of a quick loss analysis that is evaluated in the present paper. It is shown that for an accurate analysis the distributed character of the series resistance and the network character of the solar cell cannot be neglected. An advanced current-voltage curve analysis including fill factors and fit is presented.
Bifacial solar cells and modules are a promising approach to increase the energy output of photovoltaic systems, and therefore decrease levelized cost of electricity (LCOE). This work discusses the bifacial silicon solar cell concepts PERT (passivated emitter, rear totally diffused) and BOSCO (both sides collecting and contacted) in terms of expected module cost and LCOE based on in-depth numerical device simulation and advanced cost modelling. As references, Al-BSF (aluminium back-surface field) and PERC (passivated emitter and rear) cells with local rear-side contacts are considered. In order to exploit their bifacial potential, PERT structures (representing cells with single-sided emitter) are shown to require bulk diffusion lengths of more than three times the cell thickness. For the BOSCO concept (representing cells with double-sided emitter), diffusion lengths of half the cell thickness are sufficient to leverage its bifacial potential. In terms of nominal LCOE, BOSCO cells are shown to be cost-competitive under monofacial operation compared with an 18% efficient (≙ pMPP = 18 mW/cm2) multicrystalline silicon (mc-Si) Al-BSF cell and a 19% mc-Si PERC cell for maximum output power densities of pMPP ≥ 17.3 mW/cm2 and pMPP ≥ 18.1 mW/cm2, respectively. These values assume the use of $10/kg silicon feedstock for the BOSCO and $20/kg for the Al-BSF and PERC cells. For the PERT cell, corresponding values are pMPP ≥ 21.7 mW/cm2 and pMPP ≥ 22.7 mW/cm2, respectively, assuming the current price offset (≈50%, at the time of October 2014) of n-type Czochralski-grown silicon (Cz-Si) compared with mc-Si wafers. The material price offset of n-type to p-type Cz-Si wafers (≈15%, October 2014) currently accounts for approximately 1 mW/cm2, which correlates to a conversion efficiency difference of 1%abs for monofacial illumination with 1 sun. From p-type mc-Si to p-type Cz-Si (≈30% wafer price offset, October 2014), this offset is approximately 2.5 mW/cm2 for a PERT cell. When utilizing bifacial operation, these required maximum output power densities can be transformed into required minimum rear-side illumination intensities for arbitrary front-side efficiencies ηfront by means of the performed numerical simulations. For a BOSCO cell with ηfront = 18%, minimum rear-side illumination intensities of ≤ 0.02 suns are required to match a 19% PERC cell in terms of nominal LCOE. For an n-type Cz-Si PERT cell with ηfront = 21%, corresponding values are ≤ 0.11 suns with 0.05 suns being the n-type to p-type material price offset. This work strongly motivates the use of bifacial concepts to generate lowest LCOE
In this paper we give a mathematical derivation of how luminescence images of silicon solar cells can be calibrated to local junction voltage. We compare two different models to extract spatially resolved physical cell parameters from voltage images. The first model is the terminal connected diode model, where each pixel is regarded as a diode with a certain dark saturation current, which is connected via a series resistance with the terminal. This model is frequently used to evaluate measurement data of several measurement techniques with respect to local series resistance. The second model is the interconnected diode model, where the diode on one pixel is connected with the neighbor diodes via a sheet resistance. For each model parameter at least one image is required for a coupled determination of the parameters. We elaborate how also the voltage calibration can be added as an unknown parameter into the models, and how the resulting system of equations can be solved analytically. Finally the application of the models and the different ways of voltage calibration are compared experimentally
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.