Chitosan-silica porous hybrids were prepared by a novel strategy in order to improve the mechanical properties of chitosan (CHT) in the hydrogel state. The inorganic silica phase was introduced by sol-gel reactions in acidic medium inside the pores of already prepared porous scaffolds. In order to make the scaffolds insoluble in acidic media chitosan was cross-linked by genipin (GEN) with an optimum GEN concentration of 3.2 wt.%. Sol-gel reactions took place with Tetraethylorthosilicate (TEOS) and 3-glycidoxypropyltrimethoxysilane (GPTMS) acting as silica precursors. GPTMS served also as a coupling agent between the free amino groups of chitosan and the silica network. The morphology study of the composite revealed that the silica phase appears as a layer covering the chitosan membrane pore walls. The mechanical properties of the hybrids were characterized by means of compressive stress-strain measurements. By immersion in water the hybrids exhibit an increase in elastic modulus up to two orders of magnitude.

In this research, composites based on thermoplastic olefin (TPO) elastomers reinforced with natural fibers were developed, having had very interesting results, aiming toward an application in the automotive industry, for manufacturing car interior components. For the first time, sisal and coir fibers were used as reinforcement of TPO composites. The best-performing samples have had a successfully reduced maximum elongation and improved both maximum stress and Young's modulus values. Different compositions were studied regarding several parameters: type of fiber (coir or sisal treated and nontreated), coupling agent presence (maleic anhydride grafted polypropylene [MAPP]) and fiber content. Overall, the presence of fibers has had a clear positive impact on the composites' mechanical properties, enhanced by the presence of MAPP, mostly when using 4% (w/w) of fiber content. The fibers' surface treatment was especially important in this work, enabling the evaluation of the fibers' alkali treatment's influence in the final mechanical properties of the composites. The treatment successfully removed some of the most hydrophobic constituents of the natural fibers, like lignin, improving the possibility of a better adhesion of the fibers to the matrix. Finally, the mechanical properties of the composites were evaluated, and it was concluded that the alkali pretreatment had a very positive effect on several of them, aided by the presence of MAPP. POLYM. COMPOS., 40:3472-3481, 2019.

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A novel approach to reinforce polymer porous membranes is presented. In the prepared hybrid materials, the inorganic phase of silica is synthesized in-situ and inside the pores of aminolyzed polylactic acid (PLA) membranes by sol-gel reactions using tetraethylorthosilicate (TEOS) and glycidoxypropyltrimethoxysilane (GPTMS) as precursors. The hybrid materials present a porous structure with a silica layer covering the walls of the pores while GPTMS serves also as coupling agent between the organic and inorganic phase. The adjustment of silica precursors ratio allows the modulation of the thermomechanical properties. Culture of mesenchymal stem cells on these supports in osteogenic medium shows the expression of characteristic osteoblastic markers and the mineralization of the extracellular matrix.