Gadolinium substituted cobalt ferrite CoGd x Fe 2−x O 4 (x = 0, 0.04, 0.08) powders have been prepared by a sol-gel autocombustion method. XRD results indicate the production of a single cubic phase of ferrites. The lattice parameter increases and the average crystallite size decreases with the substitution of Gd 3+ ions. SEM shows that the ferrite powers are nanoparticles. Room temperature Mössbauer spectra of CoGd x Fe 22−x O 4 are two normal Zeeman-split sextets, which display ferrimagnetic behavior. The saturation magnetization decreases and the coercivity increases by the Gd 3+ ions.
Zinc substituted magnesium ferrite nanomaterials Mg 1− Zn Fe 2 O 4 ( = 0, 0.1, 0.3, 0.5, 0.7) powders have been prepared by a solgel autocombustion method. The lattice parameter increases with increase in Zn concentration, but average crystallite size tends to decrease by increasing the zinc content. SEM results indicate the distribution of grains and morphology of the samples. Some particles are agglomerated due to the presence of magnetic interactions among particles. Room temperature Mössbauer spectra of Mg 1− Zn Fe 2 O 4 shows that the A Mössbauer absorption area decreases and the B Mössbauer absorption area increases with zinc concentration increasing. The change of the saturation magnetization can be explained with Néel's theory. It was confirmed that the transition from ferrimagnetic to superparamagnetic behaviour depends on increase in zinc concentration by Mössbauer spectra at room temperature. Saturation magnetization increases and coercivity decreases with Zn content increasing.
Zinc ion-substituted cobalt ferrite powders Co1−xZnxFe2O4 (x = 0–0.7) were prepared by the sol-gel auto-combustion process. The structural properties and magnetic of the samples were investigated with X-ray diffraction (XRD), superconducting quantum interference device, and a Mössbauer spectrometer. The results of XRD showed that the powder of a single cubic phase of ferrites calcined when kept at 800 °C for 3 h. The lattice constant increases with increase in Zn concentration, but average crystallite size does not decrease constantly by increasing the zinc content, which is related to pH value. It was confirmed that the transition from ferrimagnetic to superparamagnetic behaviour depends on increasing zinc concentration by Mössbauer spectra at room temperature. Magnetization at room temperature increases for x ≤ 0.3, but decreases for increasing Zn2+ ions. The magnetization of Co0.7Zn0.3Fe2O4 reached maximum value (83.51 emu/g). The coercivity decreased with Zn2+ ions, which were doped on account of the decrease of the anisotropy constant.
Zinc substituted magnesium ferriteMg1-xZnxFe2O4(x=0.5,0.7)powders have been prepared by a sol-gel autocombustion method. XRD patterns show that the specimens withx=0.5and 0.7 exhibit single-phase spinel structure, and more content of Zn in specimens is favorable for the synthesis of pure Mg-Zn ferrites. Room temperature Mössbauer spectra ofMg1-xZnxFe2O4annealed at 800°C display transition from ferrimagnetic behavior to super paramagnetic behavior with increase in zinc concentration. The Mössbauer spectras of Mg0.5Zn0.5Fe2O4annealed at different temperatures display the magnetic phase change of the ferrite particles.
Cobalt-chromium ferrite, CoCrxFe2−xO4 (x = 0–1.2), has been synthesized by the sol-gel auto-combustion method. X-ray diffraction (XRD) indicates that samples calcined at 800 °C for 3 h were a single-cubic phase. The lattice parameter decreased with increasing Cr concentration. Scanning electron microscopy (SEM) confirmed that the sample powders were nanoparticles. It was confirmed from the room temperature Mössbauer spectra that transition from the ferrimagnetic state to the superparamagnetic state occurred with the doping of chromium. Both the saturation magnetization and the coercivity decreased with the chromium doping. With a higher annealing temperature, the saturation magnetization increased and the coercivity increased initially and then decreased for CoCr0.2Fe1.8O4.
The present study envisages the preparation of chromium substituted Nickel ferrite NiCrxFe2−xO4 (x = 0~1.0) powders by a sol-gel auto-combustion method. X-ray diffraction analysis (XRD) showed that the specimens with x > 0.2 exhibited a single-phase spinel structure, and that more content of Cr within a specimen is favorable for the synthesis of pure Ni-Cr ferrites. The lattice parameter decreased with an increase in the Cr concentration. The sample without calcining exhibited a good crystallinity. Scanning Electron Microscopy (SEM) showed the formation of ferrite powders nano-particles, and that the substitution of Cr weakened the agglomeration between the particles. Mössbauer spectra of NiCrxFe2−xO4 showed two normal Zeeman-split sextets that displayed a ferrimagnetic behavior. Furthermore, the spectra indicated that iron was in the Fe3+ state, and the magnetic hyperfine field at the tetrahedral tended to decrease with an increase in the Cr substitution. The saturation magnetization decreased by the Cr3+ ions, and reached a minimum value (Ms = 4.46 emu/g). With an increase in the annealing temperature, the coercivity increased initially, which later decreased.
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