A robust NNS-manganese(i) complex has been developed that can efficiently catalyze the dehydrogenation coupling of γ-amino alcohols with ketones or secondary alcohols in a one-step synthesis of quinolines and pyridines with high yields.

Gadolinium substituted cobalt ferrite CoGd x Fe 2−x O 4 (x = 0, 0.04, 0.08) powders have been prepared by a sol-gel autocombustion method. XRD results indicate the production of a single cubic phase of ferrites. The lattice parameter increases and the average crystallite size decreases with the substitution of Gd 3+ ions. SEM shows that the ferrite powers are nanoparticles. Room temperature Mössbauer spectra of CoGd x Fe 22−x O 4 are two normal Zeeman-split sextets, which display ferrimagnetic behavior. The saturation magnetization decreases and the coercivity increases by the Gd 3+ ions.

Recent developments within our group of voice sourcevocal tract acoustic interaction are reviewed. Special emphasis is layed on nonlinear superposition phenomena, i.e., how the excitation within a period is dependent on the past history of vocal tract oscillations and their residual components within the transglottal pressure. A study of breathy phonation shows that constant leakage affects the voice source slope less than does the dynamic leakage in terms of a residual closing phase. A simulation of a female voice source is attempted.

Metal-organic framework (MOF) solids with their variable functionalities are relevant for energy conversion technologies. However, the development of electroactive and stable MOFs for electrocatalysis still faces challenges. Here, a molecularly engineered MOF system featuring a 2D coordination network based on mercaptan-metal links (e.g., nickel, as for Ni(DMBD)-MOF) is designed. The crystal structure is solved from microcrystals by a continuous-rotation electron diffraction (cRED) technique. Computational results indicate a metallic electronic structure of Ni(DMBD)-MOF due to the Ni-S coordination, highlighting the effective design of the thiol ligand for enhancing electroconductivity. Additionally, both experimental and theoretical studies indicate that (DMBD)-MOF offers advantages in the electrocatalytic oxygen evolution reaction (OER) over non-thiol (e.g., 1,4-benzene dicarboxylic acid) analog (BDC)-MOF, because it poses fewer energy barriers during the rate-limiting *O intermediate formation step. Iron-substituted NiFe(DMBD)-MOF achieves a current density of 100 mA cm −2 at a small overpotential of 280 mV, indicating a new MOF platform for efficient OER catalysis.

Zinc substituted magnesium ferrite nanomaterials Mg 1− Zn Fe 2 O 4 ( = 0, 0.1, 0.3, 0.5, 0.7) powders have been prepared by a solgel autocombustion method. The lattice parameter increases with increase in Zn concentration, but average crystallite size tends to decrease by increasing the zinc content. SEM results indicate the distribution of grains and morphology of the samples. Some particles are agglomerated due to the presence of magnetic interactions among particles. Room temperature Mössbauer spectra of Mg 1− Zn Fe 2 O 4 shows that the A Mössbauer absorption area decreases and the B Mössbauer absorption area increases with zinc concentration increasing. The change of the saturation magnetization can be explained with Néel's theory. It was confirmed that the transition from ferrimagnetic to superparamagnetic behaviour depends on increase in zinc concentration by Mössbauer spectra at room temperature. Saturation magnetization increases and coercivity decreases with Zn content increasing.

Zinc ion-substituted cobalt ferrite powders Co1−xZnxFe2O4 (x = 0–0.7) were prepared by the sol-gel auto-combustion process. The structural properties and magnetic of the samples were investigated with X-ray diffraction (XRD), superconducting quantum interference device, and a Mössbauer spectrometer. The results of XRD showed that the powder of a single cubic phase of ferrites calcined when kept at 800 °C for 3 h. The lattice constant increases with increase in Zn concentration, but average crystallite size does not decrease constantly by increasing the zinc content, which is related to pH value. It was confirmed that the transition from ferrimagnetic to superparamagnetic behaviour depends on increasing zinc concentration by Mössbauer spectra at room temperature. Magnetization at room temperature increases for x ≤ 0.3, but decreases for increasing Zn2+ ions. The magnetization of Co0.7Zn0.3Fe2O4 reached maximum value (83.51 emu/g). The coercivity decreased with Zn2+ ions, which were doped on account of the decrease of the anisotropy constant.

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